Scientific American Supplement, No. 344, August 5, 1882Various
Science
Scientific American Supplement, No. 344, August 5, 1882
Various
Science -- Periodicals
to be, though it is not quite clear to me how it can be so if steel is
a chemical compound. However this may be, we know that a piece of good
soft steel breaks with a fine crystalline fracture, and the same piece
hardened when broken shows either an amorphous structure or one very
finely crystalline, which would indicate that the crystals had been
broken up by the action of heat, and that they had not had sufficient
time to return to their original position on account of the sudden
cooling. The tendency of the molecules of steel after hardening to
assume their natural position when cold seems to be very great, for we
have often seen large pieces of steel burst asunder after hardening,
though lying untouched, and sometimes with such force as to hurl the
fragments to some distance. If a piece of steel be subjected to a bright
yellow or white heat its nature is entirely changed, and the workman
says it is burnt. Though this is not actually a fact, it does well
enough to express that condition of the metal. Steel cannot be burnt
unless some portion of it has been oxidized. The carbon would of course
be attacked first, its affinity for oxygen being greatest; but we find
nothing wanting in a piece of burnt steel. It can, by careful heating,
hammering and hardening, be returned to its former excellence. Then what
change has taken place? I should say that two modifications have been
made, one physical, the other chemical. The change chemically is that
of a chemical compound to a mixture of carbon and iron, so that in a
chemical sense it resembles cast iron. The change physically is that of
crystallization, being due partly to chemical change and partly to the
effect of heat. I have procured a specimen of steel showing beautifully
the effect of overheating. The specimen is labeled No. 1, and is a piece
of Park Brothers' steel (one of the best brands made in America). It has
been heated at one end to proper heat for hardening, and at the other is
what is technically called "burnt." It has been broken at intervals
of about 1½ inches, showing the transition from amorphous or proper
hardening to highly crystalline or "burnt." Malleable or wrought iron
is or should be pure iron. Of course in practice it is seldom such, but
generally nearly so, being usually 98, 99, or even more per cent. It is
exceedingly prone to crystallization, the purer varieties being as much
subject to it as others, except those contaminated with phosphorus,
which affects it similarly with steel, and makes it very weak to cross
and tensile strains. I have never estimated the quantity present in any
except one specimen, a bar of 1½ round, which literally fell to pieces
when dropped across a block of iron. It had 1.32 per cent. of phosphorus
and was very crystalline, though the crystals were not very large. Iron
which has been, when first made, quite fibrous, when subjected to a
series of shocks for a greater or less period, according to their
Public-domain text, read in full here on John Shaqi.
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