Scientific American Supplement, No. 363, December 16, 1882 — John Shaqi
Scientific American Supplement, No. 363, December 16, 1882Various
Science
Scientific American Supplement, No. 363, December 16, 1882
Various
Science -- Periodicals
[Footnote 1: _Vide_ Burgh, "Modern Marine Engineering," page 176 _et
seq._ M. Cousté, _Annales des Mines_ V 69. _Recherches sur Vincrustation
des Chaudières a vapour_. Mr. Hugh Lee Pattison, of Newcastle-on-Tyne,
at the meeting of the Institute of Mechanical Engineers of Great
Britain, in August, 1880, remarked on this subject that "The solubility
of sulphate of lime in water diminishes as the temperature rises. At
ordinary temperatures pure water dissolves about 150 grains of sulphate
of lime per gallon; but at a temperature of 250° Fahr., at which the
pressure of steam is equal to about 2 atmospheres, only about 40 grains
per gallon are held in solution. At a pressure of 3 atmospheres, and
temperature of 302° Fahr., it is practically insoluble. The point
of maximum solubility is about 95° Fahr. The presence of magnesium
chloride, or of calcium chloride, in water, diminishes its power of
dissolving sulphate of lime, while the presence of sodium chloride
increases that power. As an instance of the latter fact, we find a
boiler works much cleaner which is fed alternately with fresh water and
with brackish water pumped from the Tyne when the tide is high than one
which is fed with fresh water constantly."]
These figures hold substantially for fresh as well as for sea water, for
the sulphate of lime becomes wholly insoluble in sea water, or in soft
water, at temperatures comprised between 280° and 300° Fahr.
It appears from this that it is simply necessary to heat water up to a
temperature of 250° in order to effect the precipitation of four fifths
of the sulphate of lime it may have contained, or to the temperature of
290° in order to precipitate it entirely. The bearing of these facts on
the purification of feed-waters will appear further on. The explanation
offered to account for the gradually increasing insolubility of sulphate
of lime on heating, is, that the hydrate, in which condition it exists
in solution, is partially decomposed, anhydrous calcic sulphate
being formed, the dehydration becoming more and more complete as the
temperature rises. Sulphate of magnesia, chloride of sodium (common
salt), and all the other more soluble salts contained in natural waters
are likewise precipitated by the process of supersaturation, but owing
to their extreme solubility their precipitation will never be effected
in boilers; all mechanically suspended matter tends naturally to
subside.
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