Scientific American Supplement, No. 365, December 30, 1882Various
Science
Scientific American Supplement, No. 365, December 30, 1882
Various
Science -- Periodicals
3. The volatility of free silicon at a high temperature is too slight to
account for the alteration of the platinum at a distance. This can be
shown by placing several decigrammes of crystallized silicon on the
bottom of a small crucible of retort carbon, covering the silicon with a
small flat disk of retort carbon upon which is placed the slip of
platinum. The crucible, closed by its turned cover, is then enveloped in
a titaniferous packing and kept at a brilliant white heat for an hour
and a half. The metal is found to have only very slightly increased in
weight, and its properties remain unaltered. This experiment was
repeated several times with the same result. If, however, the
crystallized silicon be replaced by powdered calcined silica, the
platinum, placed upon the carbon disk, fuses and increases in weight,
while the silica loses weight. The theory of these curious phenomena is
very difficult to establish on account of the high temperatures which
are necessary for their manifestation, but it may be concluded, at
present, that nitrogen and probably oxygen also play some part in the
transportation of the silicon across the intervening space, and that the
carbosilicious compounds recently described by MM. Schuetzenberger and
Colson also take part in the phenomenon.--_Comptes Rendus_, xciv.,
1,710.--_Amer. Chem. Journal._
* * * * *
STANNOUS NITRATES.
At the Royal Powder Works at Spandau, Prussia, frequent ignition of the
powder at a certain stage of the process led to an examination of the
machinery, when it was found that where, at certain parts, bronze pieces
which were soldered were in constant contact with the moist powder, the
solder was much corroded and in part entirely destroyed, and that in the
joints had collected a substance which, on being scraped out with a
chisel, exploded with emission of sparks. It was suspected that the
formation of this explosive material was in some way connected with the
corrosion of the solder, and the subject was referred for investigation
to Rudolph Weber, of the School of Technology, at Berlin. The main
results of his investigation are here given.
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