Scientific American Supplement, No. 365, December 30, 1882Various
Science
Scientific American Supplement, No. 365, December 30, 1882
Various
Science -- Periodicals
And here we find ourselves face to face with a question of great
delicacy and importance. Both as a radiator and as an absorber, carbonic
acid is, in general, a feeble gas. It is beaten in this respect by
chloride of methyl, ethylene, ammonia, sulphurous acid, nitrous oxide,
and marsh gas. Compared with some of these gases, its behavior, in fact,
approaches that of elementary bodies. May it not help to explain their
neutrality? The doctrine is now very generally accepted that atoms of
the same kind may, like atoms of different kinds, group themselves to
molecules. Affinity exists between hydrogen and hydrogen and between
chlorine and chlorine, as well as between hydrogen and chlorine. We have
thus homogeneous molecules as well as heterogeneous molecules, and the
neutrality so strikingly exhibited by the elements may be due to a
quality of which carbonic acid furnishes a partial illustration. The
paired atoms of the elementary molecules may be so out of accord with
the periods of the ultra red waves--the vibrating periods of these atoms
may, for example, be so rapid--as to disqualify them both from emitting
those waves, and from accepting their energy. This would practically
destroy their power, both as radiators and absorbers. I have reason to
know that a distinguished authority has for some time entertained this
hypothesis.
We must, however, refresh ourselves by occasional contact with the solid
ground of experiment, and an interesting problem now lies before us
awaiting experimental solution. Suppose two hundred men to be scattered
equably throughout the length of Pall Mall. By timely swerving now and
then, a runner from St. James's Palace to the Athenaeum Club might be
able to get through such a crowd without much hinderance. But supposing
the men to close up so as to form a dense file crossing Pall Mall from
north to south; such a barrier might seriously impede, or entirely stop,
the runner. Instead of a crowd of men, let us imagine a column of
molecules under small pressure, thus resembling the sparsely distributed
crowd. Let us suppose the column to shorten, without change in the
quantity of matter, until the molecules are so squeezed together as to
resemble the closed file across Pall Mall. During these changes of
density, would the action of the molecules upon a beam of heat passing
among them at all resemble the action of the crowd upon the runner?
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