Scientific American Supplement, No. 365, December 30, 1882Various
Science
Scientific American Supplement, No. 365, December 30, 1882
Various
Science -- Periodicals
We must answer this question by direct experiment. To form our molecular
crowd we place, in the first instance, a gas or vapor in a tube 38
inches long, the ends of which are closed with circular windows,
air-tight, but formed of a substance which offers little or no
obstruction to the calorific waves. Calling the measured value of a heat
beam passing through this tube 100, we carefully determine the
proportionate part of this total absorbed by the molecules in the tube.
We then gather precisely the same number of molecules into a column 10.8
inches long, the one column being thus three and a half times the length
of the other. In this case also we determine the quantity of radiant
heat absorbed. By the depression of a barometric column, we can easily
and exactly measure out the proper quantities of the gaseous body. It is
obvious that one mercury inch of vapor, in the long tube, would
represent precisely the same amount of matter--or, in other words, the
same number of molecules--as 31/2 inches in the short one; while 2
inches of vapor in the long tube would be equivalent to 7 inches in the
short one.
The experiments have been made with the vapors of two very volatile
liquids, namely, sulphuric ether and hydride of amyl. The sources of
radiant heat were, in some cases, an incandescent lime cylinder, and in
others a spiral of platinum wire, heated to bright redness by an
electric current. One or two of the measurements will suffice for the
purposes of illustration. First, then, as regards the lime light; for 1
inch of pressure in the long tube, the absorption was 18.4 per cent. of
the total beam; while for 3.5 inches of pressure in the short tube, the
absorption was 18.8 per cent., or almost exactly the same as the former.
For 2 inches pressure, moreover, in the long tube, the absorption was
25.7 per cent.; while for 7 inches in the short tube it was 25.6 per
cent. of the total beam. Thus closely do the absorptions in the two
cases run together--thus emphatically do the molecules assert their
individuality. As long as their number is unaltered, their action on
radiant heat is unchanged. Passing from the lime light to the
incandescent spiral, the absorptions of the smaller equivalent
quantities, in the two tubes, were 23.5 and 23.4 per cent.; while the
absorptions of the larger equivalent quantities were 32.1 and 32.6 per
cent., respectively. This constancy of absorption, when the density of a
gas or vapor is varied, I have called "the conservation of molecular
action."
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