Scientific American Supplement, No. 385, May 19, 1883Various
Science
Scientific American Supplement, No. 385, May 19, 1883
Various
Science -- Periodicals
"When the element is used up, and, notably, when all the chloride of
silver is reduced, it is only necessary to plunge the carbon with its
asbestos covering (after washing it in water) into a chloridizing bath,
in order to bring back the metallic silver that invests the carbon to a
state of chloride, and thus restore the pile to its primitive energy.
After this the carbon is washed and put back into the exciting liquid.
"These reductions of the chloride of silver during the operation of the
pile can be reproduced _ad infinitum_, since they are accompanied by no
loss of metal. The alkaline liquid is sufficient in quantity for two
successive charges of the couple.
"The chloridizing bath consists of 100 parts of acetic acid, 5 to 6
parts, by weight, of hydrochloric acid, and about 30 parts of water.
[Illustration: FIG. 1.--SCRIVANOW'S CHLORIDE OF SILVER PILE.]
"Other acids may be employed equally as well. A bath composed of
chlorochromate of potassium and nitric or sulphuric acid makes an
excellent regenerator.
"To sum up, I claim as the distinctive characters of my pile:
"1. The use of the potassic or sodic alkaline liquid conjointly with
chloride of silver, and the oxide of the same, that forms through the
immersion of the carbon in a chloridizing bath.
"2. The use of retort or other carbon covered with the salt of silver
above specified.
"3. The arrangement and construction of my pile as I have described."
In the experiments recently tried with Mr. Scrivanow's pile, a large
sized battery was made use of, whose dimensions were 300 x 145 x 125
millimeters, and whose weight was from 5 to 6 kilogrammes. The results
were: intensity, 1 ampere; electro-motive power, 25 volts, corresponding
to an energy of 25 volt-amperes, or about 2.5 kilogrammeters per second.
The pile was covered with a copper jacket whose upper parts supported
two Swan lamps. Upon putting on the cover a contact was formed with the
electrodes, and it was possible by means of a commutator key with three
eccentrics to light or extinguish one of the lamps or both at once.
A single element would have sufficed to keep one Swan lamp of feeble
resistance lighted for 20 hours. Accepting the data given above and
the 20 hours' uninterrupted duration of the pile's operation the power
furnished by this large model is equal to 2.5 x 20 x 3,600 = 180,000
kilogrammeters.
[Illustration: FIG. 1.--SCRIVANOW'S CHLORIDE OF SILVER PILE.]
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