Scientific American Supplement, No. 401, September 8, 1883Various
Science
Scientific American Supplement, No. 401, September 8, 1883
Various
Science -- Periodicals
In the application of electrolysis to the bleaching of textile
materials, it is only necessary to have the electrodes of any
sufficiently powerful generator of electricity end in a vessel
containing in aqueous solution such decolorizing agents as the
hypochlorites in general, and chlorides, bromides, and iodides that are
capable of disengaging chlorine, and iodine or an iodide in a nascent
state. These gases perform the role of oxidizing or decolorizing agents.
The fibers that are immersed in the solution during the passage of the
electric current must necessarily remain therein for a greater or less
length of time, according to the nature of the material to be bleached,
and must, after this first operation, be washed, rinsed, and dried.
The use of an electric current for decomposing the metallic chlorides
and disengaging their elements is not new, and there have been specially
utilized for this purpose, up to the present time, the alkaline
hypochlorites that are obtained by well known processes.
In the latter case the metal is brought to the state of oxide in
presence of the water that is necessary for the reaction. But the
results obtained in practicing this method are deceiving, as far as
bleaching is concerned, and it is evidently more rational and economical
to endeavor to compound the hypochlorite directly by borrowing all its
elements from the metallic chloride itself, and from the water by means
of which such transformation is to be effected. This is a reversal of
the problem, and, _à propos_ thereof, we would call the attention of
the reader to an apparatus invented by Messrs. Naudin & Schneider for
effecting such synthesis in a simple and practical manner.
If a solution of chloride of sodium or kitchen salt, NaCl, be submitted
to electrolysis in a hermetically closed vessel containing the material
to be bleached, a formation of hypochlorite of soda is produced in the
following way:
2NaCl + 2 H_{2}O = NaCl + NaO, ClO + 4H.
In operating in this manner we shall have the advantage that results
from the nascent body through the electrical double decomposition of the
chloride of sodium and water, which puts the chlorine, the metal, the
hydrogen, and the oxygen simultaneously in presence. The chlorine and
oxygen will combine their action to decolorize the textile material.
While starting from this idea, it will nevertheless be preferable to
adopt Naudin & Schneider's arrangement.
The apparatus consists of a hermetically closed electrolyzer, A,
into the lower part of which enters the electrodes, E and F, of any
electrical machine whatever. The receptacle, A, is provided with a
safety-tube, T, that issues from its upper part and communicates with
a reservoir, B. A second tube, D, forms a communication between the
electrolyzer and the vessel, C. The liquid contained in this latter is
sucked up by a pump, P, and forced to the lower part of the vessel, A,
by means of the tubes, G and H.
The apparatus operates as follows:
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