Scientific American Supplement, No. 401, September 8, 1883Various
Science
Scientific American Supplement, No. 401, September 8, 1883
Various
Science -- Periodicals
Besides the difference of sensitiveness toward the solar spectrum, these
modifications of silver bromide exhibit other characteristic differences
in properties which indicate beyond a doubt that they are two
essentially different modifications of the same substance. Among these
are, 1st. Their unequal divisibility in gelatin or collodion solutions.
The indigo sensitive silver bromide cannot be distributed through a
gelatin solution, while the blue sensitive modification does so very
readily. 2d. Their unequal reducibility; the blue sensitive silver
bromide being reduced with much greater difficulty than the indigo
sensitive variety. 3d. Their different action toward chemical and
physical sensitizers. 4th. Their different action toward photographic
developers. 5th. Their different action under the influence of heat.
The blue sensitive variety if heated under water has its sensitiveness
perceptibly increased, while the other is not changed by such treatment.
A direct transformation of one modification into the other has not yet
been accomplished. The effect of the light upon these substances is
incipient reduction, and we might hence suppose that the more reducible
indigo sensitive variety would be the more sensitive to light. But
this is not the case, because it is not chemical reducibility, but the
absorption power for light that is of the greatest importance. Now the
blue sensitive silver bromide has a greater absorption power than the
indigo sensitive variety, and hence its greater sensitiveness. Silver
chloride prepared by methods similar to those used in making the two
forms of bromides was also found to exist in two modifications. One is
designated as ultra violet sensitive, the other as violet sensitive
silver chloride.--_Amer. Chem. Jour_.
* * * * *
ANALYSIS OF A SAMPLE OF NEW ZEALAND COAL.
[Footnote: Read before the Society of Public Analysts on the 28th June,
1883.]
By OTTO HEHNER
Some discussion having recently taken place as to the value of New
Zealand coal as a fuel, the following results of a somewhat full
analysis may be worthy of being placed on record.
The sample to which the results refer consisted of large brownish
black lumps, many of which showed woody structure; the fractures were
conchyloid, the surface shiny and highly reflecting. It was interspersed
with a considerable amount of an amber colored resin. When powdered it
appeared chocolate brown. It burned readily, the flame being bright and
very smoky. Its ash was light and reddish brown.
It consisted of--
Water (loss at 212° F.) 20.09
Organic and volatile matter 75.19
Ash 4.72
------
100.00
The organic and volatile constituents had the following percentage
composition--
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