Scientific American Supplement, No. 401, September 8, 1883Various
Science
Scientific American Supplement, No. 401, September 8, 1883
Various
Science -- Periodicals
The extraordinary sensitiveness of silver bromide in gelatin seemed the
more remarkable since it was known that silver bromide in collodion is
only moderately sensitive. The explanation was sought for in various
directions, but as the result of numerous investigations it appears
that the chief cause of the difference is the presence of different
modifications of silver bromide. From a consideration of the work
already done on the subject, Vogel suspected that silver bromide
precipitated in an aqueous colloidal liquid would have notably different
properties from silver bromide precipitated in an alcoholic colloidal
solution. Silver bromide was prepared in many different ways. Emulsions
were made in bromide solutions containing gelatin or collodion (the
former aqueous, the latter alcoholic), some with the aid of heat, others
without. Part of the emulsion was then poured upon plates kept at a
moderate temperature and dried. The remainder was boiled or treated with
ammonia before being applied to the plates. He also precipitated silver
bromide in dilute gelatin or collodion solutions, allowed it to settle
completely, washed the precipitate, and mixed it with a new portion
of gelatin or collodion before applying it to the plates. Finally he
precipitated pure silver bromide, in the absence of all colloids, by
means of pure aqueous or alcoholic solutions of bromides and attempted
to bring this upon plates, using gelatin or collodion as a cement.
The result of all these experiments is that there are essentially two
modifications of silver bromide, the one being obtained by precipitation
in aqueous, the other in alcoholic solutions. The first, on account of
the position of the maximum of sensitiveness for the solar spectrum, he
calls blue sensitive, the other, for the same reason, indigo sensitive.
It is of no consequence whether the aqueous or alcoholic solution in
which the silver bromide is formed contains gelatin or collodion, or
whether the precipitation is effected with excess of bromide or of
silver nitrate. It makes no difference whether the solution is hot or
cold, or whether the silver bromide is treated with ammonia or
whether it is boiled or not. The only necessary condition is that in
precipitating indigo sensitive silver bromide the solutions must contain
at least 96 per cent of alcohol. From aqueous alcoholic solutions blue
sensitive silver bromide is precipitated.
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