Scientific American Supplement, No. 441, June 14, 1884.Various
Science
Scientific American Supplement, No. 441, June 14, 1884.
Various
Science -- Periodicals
The construction of larger furnaces and the employment of higher
temperatures led to the production of a highly carbonized, fusible
metal, without any special design on the part of the manufacturers in
producing it. This pig iron, however, could be used only for a few
purposes for which metallic iron was needed; but it was produced
cheaply and with little loss of metal, and the attempt to decarbonize
this product and bring it into a state in which it could be hammered
and welded was soon successfully made. This process of decarbonization,
or some modification of it, has successfully held the field against
all so-called, direct processes up to the present time. Why? Because
the old fashioned bloomeries and Catalan forges could produce blooms
only at a high cost, and because the new processes introduced failed
to turn out good blooms. Those produced were invariably "red short,"
that is, they contained unreduced oxide of iron, which prevented the
contact of the metallic particles, and rendered the welding together
of these particles to form a solid bloom impossible.
The process of puddling cast iron, and transforming it by
decarbonization into wrought iron, has, as everybody knows, been in
successful practical operation for many years, and the direct process
referred to so closely resembles this, that a short description of the
theory of puddling is not out of place here.
The material operated on in puddling is iron containing from 21/2 to 4
per cent. of carbon. During the first stage of the process this iron
is melted down to a fluid bath in the bottom of a reverberatory
furnace. Then the oxidation of the carbon contained in the iron
commences, and at the same time a fluid, basic cinder, or slag, is
produced, which covers a portion of the surface of the metal bath, and
prevents too hasty oxidation. This slag results from the union of
oxides of iron with the sand adhering to the pigs, and the silica
resulting from the oxidation of the silicon contained in the iron.
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