Scientific American Supplement, No. 447, July 26, 1884Various
Science
Scientific American Supplement, No. 447, July 26, 1884
Various
Science -- Periodicals
The process depends on the reduction of indigo to indigo-white, or
soluble indigo, by means of hyposulphite, or, as it is generally termed
to avoid confusion with antichlore, rightly named thiosulphate of soda,
hydrosulphite of soda. The formula of this substance is NaHSO_{2}, as
distinguished from what is commonly known as hyposulphite of soda,
Na_{2}S_{2}O_{3}. It is produced by the action of zinc-dust on the acid
sulphite of soda. The zinc may be supposed to remove oxygen from the
acid sulphite, NaHSO_{3}, giving hyposulphite, NaHS0_{2}. The reduction
of the acid sulphite is best performed in a cask, which can be closed at
the top, so as to avoid entrance of air. The acid sulphite of soda, at a
strength of 50 or 60 Twaddell (specific gravity 1.26 to 1.3), is placed
in the cask, and zinc-dust is added, with frequent stirring. The liquid
is then mixed with milk of lime, and after again thoroughly stirring,
the liquid is allowed to settle, and the clear is decanted into the
dyeing-copper. The indigo, in the frothy state in which it is skimmed
from the purifying barrels or tanks, is then added, with sufficient lime
to dissolve it when it has been reduced. It is heated gently by a steam
coil, to about 90° Fahr., and the goods are dyed in it. The colors
obtained by means of this indigo are light in shade, and the goods must
be dipped several times if dark shades are required. But it is found
better in practice not to attempt to dye dark shades by this process;
the ordinary indigo-vat is better adapted for such work. The object of
not wasting indigo is sufficiently attained by employing it for the
purpose to which it is best adapted. Of course the recovered indigo may
be used in the ordinary manner. I merely mention the most convenient way
of disposing of it in works where only a small quantity is recovered,
and which do not practice dyeing on an extensive scale.
I have now to ask you to turn to a different subject, namely, the
scouring of wool, not by the usual agent, water, but by a liquid,
bisulphide of carbon, made by the action of sulphur vapor on red hot
coke or charcoal.
This, again, is not wholly a new process, for various attempts have
been made to dissolve out the yolk, or _suint_, or greasy matter from
unwashed wool, as it comes from the back of the sheep. Fusel oil
has been patented for this purpose. Carbon disulphide has also been
patented, but, as will afterward be shown, the old method of removing it
from the wool injured the color and quality of the fiber, so as to make
the application of this scouring agent a failure.
Public-domain text, read in full here on John Shaqi.
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