Scientific American Supplement, No. 467, December 13, 1884Various
Science
Scientific American Supplement, No. 467, December 13, 1884
Various
Science -- Periodicals
_Experiment_ 3.--_Platinum Toning._--The value of a platinum salt as a
toning agent for silver images has been thoroughly demonstrated before
you by Mr. Henderson, when he initiated us into the secrets of ceramic
photography. My trials with this salt as a toning agent for paper
proofs have only been partially successful. By that I mean that toning
does take place when a dilute solution is employed, but the action is
too tardy for demonstration here to-night, since anything like a black
tone could not be obtained under half an hour. You will observe that
the surface becomes covered with chloride, showing the necessity for
copious washing. Yellow or discolored prints are bleached when toned
in this bath, the whites becoming very pure. The formula here given
is capable of producing a very good shade of brown in less time, and
should be permanent, since platinum is a metal practically unaffected
by the atmosphere; and I think there is good reason to suppose that
if a thin coating of platinum could be deposited on the silver image,
the protection offered would be more economical as well as stable.
Something has already been done in this direction, but not in recent
years.
The following is the composition we are now using:
Platinum tetrachloride, sirupy solution,
color of old East India sherry 5 minims.
Hydrochloric acid 150 "
Water 20 ounces.
Wash away the free silver thoroughly, warm the toning solution to 70°
Fahr., and fix in a twenty per cent. hypo. bath.
Mr. A. Watt, in the second volume of the _News_, gives a formula which
runs as follows:
Solution of platinum 30 minims.
Hypo. 3 grains.
Hydrochloric acid 5 minims.
Water 5 ounces.
This bath is said to act instantly, but I have not had an opportunity
to test it. The strength of the platinum solution here given is
indefinite, but any of our experimental members can soon ascertain the
amount of dilution necessary to obtain the most favorable results.
_Alkaline Toning._--Owing to the bleaching action which occurs in
toning silver prints with gold, which is slightly acid, certain
experiments were made, and it was found that bleaching increased in
proportion to the quantity of hydrochloric acid added. Now, in the
action of toning chlorine is disengaged, and in order to render this
powerful bleaching agent inert it has been proposed to introduce a
substance capable of combining with it, and thus, in absorbing it,
prevent undue loss of vigor. To obtain this a slightly alkaline toning
bath became a necessity, and to Mr. Waterhouse we are indebted for the
introduction of the alkaline salts (Hardwich).
Here is an example:
_Experiment_ 4.
Sodium carbonate (Na_{2}HCO_{3}) 5 grains.
Auric terchloride (AuCl_{3}) 1 grain.
Water 10 ounces.
Public-domain text, read in full here on John Shaqi.
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