Scientific American Supplement, No. 467, December 13, 1884Various
Science
Scientific American Supplement, No. 467, December 13, 1884
Various
Science -- Periodicals
Instead of the dry bicarbonate we will use a saturated solution. In
this as well as the following experiments we shall tone three prints of
the same subject, viz., ordinary, fumed, and preserved.
Mr. Maxwell Lyte has written on and investigated the properties of
toning solutions a great deal more than most men, and we find the
following emanating from Mr. Lyte:
Sesquichloride of gold 15 grains.
Phosphate of soda 300 "
Distilled water 1¾ pints.
And in the same communication it is mentioned that 180 grains of borax
may be substituted for the phosphate with a like result. Therefore
it will be seen that a borax toning bath is not of recent discovery,
although it does not appear to have been quoted in many formulæ for at
least a dozen years after its publication.
After the publication of Mr. Lyte's formulæ it was found that other
salts behaved similarly; and among the first suggested we found sodium
acetate, the qualities of which, extolled by the introducer, Mr.
Hannaford, have since been verified by the whole photographic world.
Here is one of the ordinary formulæ:
_Experiment_ 5.
Gold terchloride 1 grain.
Sodium acetate 10 "
" chloride 10 "
Hot water 20 ounces.
Mix twenty-four hours before use. Neutralize with chalk or whitening
(carbonate of lime).
The name of M. Le Gray must be mentioned as the originator of the lime
and gold toning bath; although the original formulæ differ somewhat
from the one now used, the results are identical. The original formulæ
consisted first in washing away a portion of the free silver by soaking
the proofs for a few minutes in two changes of water, then submitting
them to the action of an auriferous bath, composed of
Terchloride of gold, 1 per cent. solution 1 part.
Hyperchloride of lime (white powder) 3 "
Distilled water 1,000 "
The action was complete in ten to fifteen minutes, when the prints
required washing in two changes of water to free them from the chloride
of lime remaining in the fibers previous to fixing in one to six of
hypo. If the tone were satisfactory at the expiration of fifteen
minutes, the ordinary washing could be proceeded with; if not, the
proofs were submitted to a final bath composed of:
Gold terchloride 2 parts.
Hypo. 200 "
Distilled water 1,200 "
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