Scientific American Supplement, No. 483, April 4, 1885Various
Science
Scientific American Supplement, No. 483, April 4, 1885
Various
Science -- Periodicals
The theory of the formation of this salt is, that one eq. of chlorine
withdraws from two eq. of the ferrocyanide of potassium, one eq. of
potassium, forming chloride of potassium, which remains in the mother
liquid. The reaction is explained by the following equation:
2(K_{2}Cfy)+Cl=K_{3}Cfy_{2}+KCl.
The radical ferridcyanogen, isomeric[2] with ferrocyanogen, is supposed
to be formed by the coalescence of two equivalents of ferrocyanogen, and
is represented by the symbol Cfdy; accordingly the formula of
ferridcyanide of potassium is K_{3}Cfdy.
[Footnote 2: Isomeric bodies, or substances different in properties yet
identical in composition, are of constant occurrence in organic
chemistry, and stand among its most peculiar features.]
Ferridcyanide of potassium has found extensive application in
photographic processes for intensifying negatives; those of Eder, in
combination with nitrate of lead, or Selle's, with nitrate of uranium;
Ander's blue intensification of gelatine negatives, Farmer's process of
reducing intensity, the coloring of diapositives, the very important blue
printing, and various others, are daily practiced in our laboratories.
The ferrocyanide of potassium is a chemical reagent of great value,
giving rise to precipitates with the neutral or slightly acid solutions
of metals, like the beautiful brown ferrocyanide of copper, and that of
lead. When a ferrocyanide is added to a solution of a sesquioxide of
iron, Prussian blue or ferrocyanide of iron is produced. The exact
composition of this remarkable substance is not distinctly stated, as
various blue compounds may be precipitated under different circumstances.
Berzelius gives the following account: 3 eq. of ferrocyanide and 2 eq. of
sesquioxide of iron are mutually decomposed, forming 1 eq. of Prussian
blue and 6 eq. of the potassa salt, which remains in solution, or
3K_{2}Cfy + 2(Fe_{2}O_{3}3NO_{3}) = Fe_{4}Cfy_{3} + 6(KO,NO_{5}). It
forms a bulky precipitate of an intense blue, is quite insoluble in water
or weak acids, with the exception of oxalic acid, with which it gives a
deep blue liquid, occasionally used as blue ink.
Ferridcyanide of potassium, added to a salt of the sesquioxide of iron,
yields no precipitate, but merely darkens the reddish-brown solution;
with protoxide of iron it gives a blue precipitate, containing
Fe_{3}Cfdy, which is of a brighter tint than that of Prussian blue, and
is known by the name of Turnbull's blue. Hence, the ferridcyanide of
potassium is as excellent a test for protoxide of iron as the yellow
ferrocyanide is for the sesquioxide.--_E., Photo. Times_.
* * * * *
FOUCAULT'S APPARATUS FOR MANUFACTURING ILLUMINATING GAS AND
HYDROGEN.
The illuminating gas and hydrogen apparatus, illustrated herewith, is
adapted to all cases in which it is desirable to manufacture gas upon a
small scale.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account