Scientific American Supplement, No. 488, May 9, 1885Various
Science
Scientific American Supplement, No. 488, May 9, 1885
Various
Science -- Periodicals
The three oils that form the subject of the examination detailed in
this paper were consigned to a London broker, with a view to their
being regularly exported from China if a market could be found for
them here: it was, therefore, necessary to ascertain what commercial
oils they resembled in character, so as to estimate to what uses they
might be applied.
TEA OIL (_Camellia oleifera_).
In color, transparency, and mobility, this oil considerably resembles
olive oil. The odor and taste, though characteristic, are not easy to
describe.
(1.) _Specific Gravity._--The specific gravity at 60 deg. F. is 917.5),
water at 60 deg. F. being taken as 1,000.
(2.) _Action of Cold._--On subjecting to the cold produced by a
mixture of pounded ice and salt, some solid fatty matter, probably
stearine, separates, adhering to the side of the tube. It takes a
longer exposure and a lower temperature than is necessary with olive
oil. I did not succeed in solidifying it, but only in causing some
deposit. Olive oil became solid, while almond and castor oil on the
other hand did not deposit at all under similar circumstances. The
lowest temperature observed was -13.3 deg. C. (8 deg. F.), the
thermometer bulb being immersed in the oil.
A few qualitative tests, viz., the action of sulphuric acid, nitric
acid (sp. gr. 1.42), and digestion, with more dilute nitric acid (1.2
sp. gr.) and a globule of mercury, were first tried.
When one drop of sulphuric acid is added to eight or ten drops of tea
oil on a white plate, the change of color observed is more like that
when almond oil is similarly treated than with any other oil, olive
oil coming next in order of similarity.
When a few drops of tea oil are boiled with thirty drops or so of
nitric acid in a small tube, the layer of oily matter, when the brisk
action has moderated, is of a light yellow color, similar in tint to
that produced from almond and olive oil under similar circumstances.
When the oil is digested with an equal volume of nitric acid (1.2 sp.
gr.), and a globule of mercury added, the whole becomes converted
into a mass of elaidin in about two hours, of the same tint as that
produced from almond oil when similarly treated.
These tests point to the fact that the oil may be considered as
resembling almond or olive oil in composition, a conclusion which is
borne out by the subsequent experiments.
(3.) _Free Acidity of Oil._--The oil was found to contain free acid
in small quantity, which was estimated by agitating a weighed quantity
with alcohol, in which the free acid dissolves while the neutral fat
does not, and titrating the alcoholic liquid with decinormal alkali,
using solution of phenol-phthalein as an indicator.
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