Scientific American Supplement, No. 488, May 9, 1885Various
Science
Scientific American Supplement, No. 488, May 9, 1885
Various
Science -- Periodicals
It was thus found that 100 grammes of the oil require 0.34 gramme of
caustic potash to neutralize the free acid. Mr. W. H. Deering (_Journ.
Soc. of Chem. Industry_, Nov., 1884) states that in seven samples of
olive oil examined by him, the minimum number for acidity was 0.86 per
cent., and the maximum 1.64 per cent., the mean being 1.28 per cent.
Tea oil compares favorably with olive oil, therefore, in respect of
acidity, a quality of which note has to be taken when considering the
employment of oil as a lubricating agent.
(4.) _Saponification of the Oil._--Considerable light is thrown on the
composition of a fixed oil by ascertaining how much alkali is required
to saponify it. In order to estimate this, a known excess of alcoholic
solution of potash is added to a weighed quantity of the oil,
contained in a stout, well-closed bottle (an India-rubber stopper is
the most convenient), which is then heated in a water oven until
the liquid is clear, no oil bubbles being visible. Phenol-phthalein
solution being added, the excess of potash is estimated by carefully
titrating with standard hydrochloric acid solution.
It was thus found that 1,000 grammes of oil would require 195.5
grammes of caustic potash to convert it entirely into potash soap.
Koettstorfer, to whom this method of analysis is due, gives 191.8, and
Messrs. F. W. and A. F. Stoddart the numbers 191 to 196, as the amounts
of caustic potash required by 1,000 parts of olive oil. The numbers
given by niger seed, cotton seed, and linseed oils are very similar to
these. These oils differ from olive and tea oil, however, in having a
higher specific gravity, and in the property they possess of drying to
a greater or less extent on exposure to air.
(5.) _The Fatty Acids Produced._--A solution of the potash soap was
treated with excess of hydrochloric acid, and after being well washed
with hot water, the cake of fatty acids was dried thoroughly and
weighed. These, insoluble in water, amounted to 93.94 per cent, of the
fat taken. The proportion dissolved in the water used for washing was
estimated by titration with alkali; the quantity of KOH required was
insignificant, equaling 0.71 per cent, of the fat originally used.
This portion was not further examined.
The insoluble fatty acids amounted, as last stated, to 93.94 per cent.
Pure olein, supposing none of the liberated acid to be dissolved in
water, would yield 95.7 per cent. of fatty acid.
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