Scientific American Supplement, No. 488, May 9, 1885Various
Science
Scientific American Supplement, No. 488, May 9, 1885
Various
Science -- Periodicals
The acid was evidently a mixture, and had no definite melting point.
It was solid at 9 deg. C., and sufficiently soft to flow at 12 deg. C.,
but did not entirely liquefy under 22 deg. C. To test its neutralizing
power, 0.9575 gramme dissolved in alcohol was titrated with decinormal
alkali; it required 34.05 c.c. This amount of pure oleic acid would
require 33.95 c.c.; of pure stearic acid, which has almost the same
molecular weight as oleic acid, 33.71 c.c.; or of pure palmitic acid,
37.4 c.c. This, taken in conjunction with the way in which the acid
melted, makes it extremely probable that it is a mixture of oleic and
stearic acids.
Additional evidence of the large proportion of oleic acid was
furnished by forming the lead salt, and treating with ether, in which
lead oleate is soluble, the stearate and palmitate being insoluble. In
this way it was found that the oleic acid obtained from the ethereal
solution of the lead salt amounted to 83.15 per cent. of the oil.
This acid was proved to be oleic, by its saturating power and its
melting point, which were fairly concordant with those of the pure
acid.
CABBAGE OIL (_Brassica, sp._).
_Appearance, etc._--The sample was of a deep brown color, of a
fluidity intermediate between olive and castor oil, and possessed a
strong, rather disagreeable odor.
_The Specific Gravity at 60 deg. Fahr._, 914.0.--The specific gravity of
rape oil and colza oil, both of which are obtained from species of the
genius _Brassica_, varies from 913.6 to 916.
_Exposure to Cold._--This oil by exposure to a temperature of -12 deg.
C. (10 deg. F.) becomes solidified in course of an hour, a bright
orange-yellow mass resulting.
_Qualitative Examination._--The three reagents before indicated were
applied to this oil.
_(a.) Sulphuric Acid._--The color produced was very marked and
characteristic; it differed considerably from any of the others
simultaneously tested, the nearest to it being olive end rape oil.
_(b.) Strong Nitric Acid._--The reaction was more violent than before,
the stratum of oil after cooling being darker in color than in the
three cases before mentioned. The reaction with rape oil was similar
in all respects.
_(c.) Elaidin Test._--The solid mass of elaidin formed was of a darker
color than that from olive, almond, and tea oil, but closely resembled
that from rape oil.
_Free Acidity._--This was estimated as above described. 100 grammes of
oil would require 0.125 gramme caustic potash. The samples of rape oil
examined by Deering (loc. cit.) were found to require from 0.21 to
0.78 KOH per 100 grammes oil.
_Saponification of the Oil._--Upon saponifying with alcoholic potash,
it was found that 1,000 grammes of oil required 175.2 grammes of
potash for complete saponification.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account