Scientific American Supplement, No. 508, September 26, 1885Various
Science
Scientific American Supplement, No. 508, September 26, 1885
Various
Science -- Periodicals
This retort consists of a cylinder, A, made of silica or other
non-conducting material, suitably embedded in a body, B, of powdered
charcoal, mineral wool, or of some other material which is not a good
conductor of heat. The rear end of the retort-cylinder is closed by
means of a carbon plate, C, which plate forms the positive electrode,
and with this plate the positive wire of the electric circuit is
connected. The outer end of the retort is closed by means of an
inverted graphite crucible, D, to which the negative wire of the
electric circuit is attached. The graphite crucible serves as a plug
for closing the end of the retort. It also forms a condensing chamber
for the zinc fumes, and it also constitutes the negative electrode.
The term "electrode" is used in this case as designating the terminals
of the circuit proper, or that portion of it which acts simply as an
electrical conductor, and not with the intention of indicating the
ends of a line between which there is no circuit connection. The
circuit between the "electrodes," so called, is continuous, being
established by means of and through the body of broken carbon
contained in the retort, A. There is no deposit made on either plate
of the decomposed constituents of the material reduced. The mouth of
the crucible is closed with a luting of clay, or otherwise, and the
opening, _d_, made in the upper side of the crucible, near its
extremity, comes entirely within the retort, and forms a passage for
the zinc fumes from the retort chamber into the condensing chamber.
The pipe, E, serves as a vent for the condensing chamber. The zinc ore
is mixed with pulverized or granular carbon, and the retort charged
nearly full through the front end with the mixture, the plug, D, being
removed for this purpose.
A small space is left at the top, as shown. After the plug has been
inserted and the joint properly luted, the electric circuit is closed
and the current allowed to pass through the retort, traversing its
entire length through the body of mixed ore and carbon. The carbon
constituents of the mass become incandescent, generating a very high
degree of heat, and being in direct contact with the ore, the latter
is rapidly and effectually reduced and distilled. The heat evolved
reduces the ore and distills the zinc, and the zinc fumes are
condensed in the condensing chamber, precisely as in the present
method of zinc making, with this important exception that, aside from
the reaction produced by heating carbon in the presence of zinc oxide,
the electric current, in passing through the zinc oxide, has a
decomposing and disintegrating action upon it, not unlike the effect
produced by an electric current in a solution. This action accelerates
the reduction, and promotes economy in the process.
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