Scientific American Supplement, No. 508, September 26, 1885Various
Science
Scientific American Supplement, No. 508, September 26, 1885
Various
Science -- Periodicals
[Illustration: FIG. 2.]
It will be seen that the subject of eutexia embraces many points of
practical importance and of theoretical interest. Thus it has been
shown by Dr. Guthrie that the desilverizing of lead in Pattinson's
process is but a case of eutexia, the separation of lead on cooling a
bath of argentiferous lead poor in silver being analogous to the
separation of ice from a salt solution. Dr. Guthrie has also shown
that eutexia may reasonably be supposed to have played an important
part in the production and separation of many rock-forming minerals.
It is with considerable diffidence that I suggest the following as an
explanation of the multitude of facts to which previous reference has
been made.
In a mixture of two substances, A and B, we have the following forces
active, tending to produce solidification:
1. The cohesion between the particles of A.
2. The cohesion between the particles of B.
3. The cohesion between the particles of A and the particles of B.
With regard to this last factor, it will be seen that there are three
cases possible:
1. The cohesion of the mixture A B may be greater than the
cohesion of A + the cohesion of B.
2. The cohesion of A B may be equal to the cohesion of A + the
cohesion of B.
3. The cohesion of A B may be less than the cohesion of A + the
cohesion of B.
Now, since cohesion tends to produce solidification, we should in the
first case expect to find the melting-point of the mixture _higher_
than the mean of the melting-points of its constituents, or the curve
of melting-points would be of the form given in _a_, Fig. 3. Here no
eutectic mixture is possible.
[Illustration: FIG. 3.]
In the second case, where cohesion A B = cohesion A + B, we should
obtain melting-points for the mixture which would agree with the mean
of the melting-points of the constituents, the curve of melting-points
would be a straight line, and again no eutectic mixture would be
possible.
In the third case, however, where cohesion A B is less than cohesion A
+ B, we should find the melting-points of the mixture lower than the
mean of the melting-points of its constituents, and the curve of
melting-points would be of the form given in _e_, Fig. 3. Here, in
those cases where the difference of cohesion on mixture is
considerable, the curve of melting-points may dip below the line _e
f_. This is the _only case_ in which a eutectic mixture is possible,
and it is, of course, found at the lowest point of the curve.
If it be true, as above suggested, that the force of cohesion is at
its minimum in the eutectic alloy, we should expect to find, in
preparing a eutectic substance, either that actual expansion took
place, or that the molecular volume would gradually increase in
passing along our curve of melting-points, from either end, for each
molecule added, and that it would obtain its greatest value at the
point corresponding to the eutectic alloy.
Public-domain text, read in full here on John Shaqi.
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