Scientific American Supplement, No. 561, October 2, 1886Various
Science
Scientific American Supplement, No. 561, October 2, 1886
Various
Science -- Periodicals
This solution is employed for the absorption of the nitric oxide. Its
strength need not be exactly known. There is no objection to a more
concentrated solution, except that which pertains to all strong
standard solutions, namely, that a small error in measurement would
then give a larger error in the results. 100 c.c. of this solution are
required for each determination, and the measurement is always made in
one and the same 100 c.c. measuring flask, which, if necessary, should
be labeled to distinguish it from that used for solution No. 2.
2. A solution of oxalic acid which is very slightly stronger than that
of the permanganate just described--that is, a solution such that one
c.c. of it will somewhat more than decompose one c.c. of the
permanganate, according to the reaction:
2KMnO_{4} + 3H_{2}SO_{4} + 5C_{2}H_{2}O_{4}.2H_{2}O =
K_{2}SO_{4} + 2MnSO_{4} + 18H_{2}O + 10CO_{2}.
The exact strength of this solution need not be known, since we only
require the difference in value between it and solution No. 1, which
is determined by means of solution No. 3. 100 c.c. of this solution
are also required for each determination, and the measurement, as in
the preceding case, is always made in the same 100 c.c. measuring
flask.
3. A dilute, carefully standardized solution of permanganate of
potassium.
The method of using these solutions is as follows: 100 c.c. of No. 1
and No. 2 are measured off (each solution in its own measuring flask),
brought together in a covered beaker glass, and acidified with dilute
sulphuric acid. The excess of oxalic acid is then determined by means
of solution No. 3.
When it is desired to make a determination of nitric acid, 100 c.c. of
solution No. 1 are measured off, and as much of it as may be
convenient is poured into the tubes, E, E, together with about a
gramme of zinc sulphate for each tube, which substance appears to
considerably facilitate the absorption of the nitric oxide by the
permanganate. When the operation is over, the contents of E, E are
poured into a beaker glass. 100 c.c. of solution No. 2 are then
measured off, and a portion, together with a little sulphuric acid,
poured into E, E, to dissolve the oxide of manganese which has
separated during the absorption of the nitric oxide. The oxide having
been dissolved, the liquid in E, E, and the rinsings of the tubes,
also the residues of permanganate and oxalic acid left in the
measuring flasks, and the rinsings from these, are all brought
together in the same beaker glass. Finally, the amount of solution
No. 3 required to decompose the excess of oxalic acid is determined.
If we subtract from the amount thus found the quantity of permanganate
required to equalize solutions Nos. 1 and 2 (previously ascertained),
we shall have the amount of permanganate actually reduced by the
nitric oxide, according to the reaction:
6KMnO_{4} + 10NO = 3K_{2}O + 6MnO + 5N_{2}O_{5};
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