Scientific American Supplement, No. 620, November 19,1887Various
Science
Scientific American Supplement, No. 620, November 19,1887
Various
Science -- Periodicals
[Illustration: THE NEWBERY-VAUTIN CHLORINATION PROCESS.]
We have specified above the objections to the old processes of
chlorination, so it may be fairly asked in what way the Newbery-Vautin
process avoids the various chemical actions which have hitherto proved
so difficult to contend with.
For any system of chlorination yet introduced it is necessary to free
the ore from sulphides. This is done by roasting according to any of
the well-known systems in vogue. It is a matter which requires great
care and considerable skill. The heat must be applied and increased
slowly and steadily. If, through any neglect on the part of the
roaster, the ore is allowed to fuse, in most cases it is best to throw
the charge away, as waste. This roasting applies equally to the Vautin
process as to any others. So on this head there is no alteration. One
of the most important advantages is not a chemical one, but is the
rapidity with which the charge can be treated. In the older styles of
treatment the time varied from thirty six to ninety hours. Now this is
accomplished in from three to six hours with a practically perfect
result. The older processes required a careful damping of the ore,
which, to get good results, must leave the ore neither too wet nor too
dry. Now "damping" is entirely done away with, and in its place water
is poured into the barrel. Pressure to the extent of four atmospheres
causes chlorine gas to leave its vaporous form. Thus the pressure
applied not only enables a strong solution of chlorine to be formed
with the water in the barrel, but forces this into contact with the
gold through every crevice in the ore. Chlorine gas also takes up any
silver which may exist in association with the gold. In the older
processes this is deposited as a film of chloride of silver around the
fine gold grains, and from its insolubility in water prevents the
absorption of the gold. The rotary motion of the barrel in the
Newbery-Vautin method counteracts this by continually rubbing the
particles together; this frees the particles from any accumulations,
so that they always present fresh surfaces for the action of the
solvent. Again, the short time the ore is in contact with the chlorine
does not allow of the formation of hydrochloric acid, which has a
tendency to precipitate the gold from its soluble form in the water
before being withdrawn from the chlorinator.
Hitherto, when the ore was very fine or contained slimes, the
difficulty of filtration was increased, sometimes in extreme cases to
such an extent that chlorination became impracticable. By the
introduction of the vacuum pump this is greatly facilitated; then by
making the action intermittent a jigging motion is given to the
material in the filter which prevents any clogging except in cases of
extreme fineness.
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