Scientific American Supplement, No. 620, November 19,1887Various
Science
Scientific American Supplement, No. 620, November 19,1887
Various
Science -- Periodicals
The advantage of using charcoal as a decomposing agent for chloride of
gold was pointed out by Mr. Newbery some twenty years ago; four or
five years since the idea was patented in the United States, but as
this was given gratis to the world years before, the patent did not
hold good. The form of precipitation generally adopted was to add
sulphate of iron to the liquid drawn from the filter. This not only
threw down the gold it contained, but also the lime and magnesia. Then
very great care was necessary, and a tedious process had to be gone
through to divide the gold from these. Now, by filtration through
charcoal everything that is soluble in hydrochloric acid passes away
with the water; for instance, lime and magnesia, which before gave
such great trouble. In passing through the charcoal, the chloride of
gold is decomposed and all fine gold particles are taken up by the
charcoal, so that it is coated by what appears to be a purple film.
Should copper be associated with the gold, the water, after running
through the charcoal filter, is passed over scrap iron, upon which the
copper is precipitated by a natural chemical action. If silver is
contained in the ore, it is found among the tailings in the filter, in
a chloride which is insoluble in water. Should the quantity prove
sufficiently large, it may be leached out in the usual way by
hyposulphites.
One of the great advantages common to all systems of chlorination is
that ores may be crushed dry and treated, so that the loss from float
gold may be avoided. Of this loss, which is most serious, we shall
have something to say on another occasion. An advantage in
amalgamation with chlorine gas instead of amalgamation with
quicksilver in the wet way, is that the ore need not be crushed so
finely. Roasting takes the place of fine crushing, as the ore from the
roasting furnace is either found somewhat spongy in texture or the
grains of silica in which fine gold may be incased are split or flawed
by the fire. For quicksilver amalgamation very fine crushing is
necessary to bring all gold particles in contact with it. Quicksilver
being so thick in substance, it will not find its way readily in and
out of a microscopically fine spongy body or through very fine flaws
in grains of silica, whereas chlorine gas or a solution of liquefied
chlorine does this, and absorbs the gold far more readily.
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