Scientific American Supplement, No. 711, August 17, 1889Various
History
Scientific American Supplement, No. 711, August 17, 1889
Various
Science -- Periodicals
Professional analytical chemists have hitherto given but little
attention to these preparations, and the employment of experienced
chemists in works is as yet far from general. The testing of dyewood
extracts in such a manner as to throw full light on their purity, the
quality of raw material from which they are prepared, their exact
commercial value their suitability for special purposes, and the
proportion and nature of any adulterants they may contain, is of
course a difficult and tedious task, and must be left to the expert
who is in possession of authentic specimens prepared by himself of all
the different extracts made from every variety and quality of raw
materials, and who combines a thorough knowledge of experimental
dyeing and printing with a large experience in the chemical
investigation of these preparations. But when the object of the
testing is merely careful comparison of the sample in question with an
original sample or previous deliveries, the case is much simplified,
and comes within the scope of the general chemist or the laboratory
attached to works. A few years ago I recommended carefully conducted
dyeing trials on woolen cloth mordanted with bichromate of potash as
the best and simplest mode adapted to such cases, and my subsequent
experience enables me to confirm that observation to the fullest
extent. Most of these extracts contain the coloring matter in two
states, the developed and the undeveloped, and an oxidizing mordant
such as bichromate of potash causes the latter as well as the former
to enter completely into combination with a metallic base; whereas
many of the other mordants, such as alumina or tin compounds, merely
take up the developed portion of the coloring matter together with
such small and variable proportions of the undeveloped as might
undergo oxidation during the process of dyeing. I would therefore
suggest dyeing trials with alumina, tin, iron, etc., only as
subsidiary tests indicating the suitability of an extract for certain
special purposes, while recommending the trial with bichromate of
potash as the one giving the best information respecting the actual
strength of the extract in relation to the raw material from which it
was obtained, and as giving a fair idea of the money value of the
sample. Cotton dyeing does not, as a general rule, afford a good means
of assaying extracts, as it is generally done under conditions which
do not admit of complete exhaustion of the dye bath, but it might
often with advantage be resorted to as an additional trial throwing
further light on the degree of oxidation or development of the
coloring matter. Printing trials are apt to give fallacious results
unless the proportion of mordant is carefully adjusted to the amount
of coloring matter present, and several trials with different
proportions would be necessary to prevent erroneous conclusions. For
the trials with bichromate of potash on wool I would recommend pieces
Public-domain text, read in full here on John Shaqi.
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