Scientific American Supplement, No. 717, September 28, 1889Various
Science
Scientific American Supplement, No. 717, September 28, 1889
Various
Science -- Periodicals
Many processes have from time to time been proposed to obtain ammonia
from other sources. The distillation of turf, which contains upward of
3 per cent. of nitrogen, has received much attention, and a large
number of inventors have endeavored to produce ammonia from the
nitrogen of the air; but none of these processes has to my knowledge
been successful on a manufacturing scale.
My attention was called to this subject at an early part of my career.
Already, as far back as 1861, I undertook experiments to utilize, for
the production of ammonia, waste leather, a waste material of animal
origin at once abundant and very rich in nitrogen, containing from 12
per cent. to 15 per cent. of this element. Distillation in iron
retorts yielded about half the nitrogen of this material in the form
of ammonia, the carbon remaining in the retorts containing still from
6 per cent. to 8 per cent. Distillation with a moderate quantity of
hydrate of lime increased the yield of ammonia only by 1 per cent. to
11/2 per cent. A rather better result was obtained by distilling the
ground residual carbon with hydrate of lime, but this operation
proceeded very slowly, and the total yield of ammonia still remained
very far below the quantity theoretically obtainable, so that I came
to the conclusion that it was more rational to utilize the leather,
reduced to powder by mechanical means, by mixing it directly with
other manures.
A few years later I became connected with a large animal charcoal
works, in which sulphate of ammonia was obtained as a by-product. Here
again I was met with the fact that the yield of ammonia by no means
corresponded with the nitrogen in the raw material and that the
charcoal remaining in the retorts contained still about half as much
nitrogen as had been present in the bones used.
From this time forward my attention was for many years given
exclusively to the soda manufacture, and it was only in 1879 that I
again took up the question of ammonia. I then determined to submit the
various processes which had been proposed for obtaining ammonia from
the nitrogen of the air to a searching investigation, and engaged Mr.
Joseph Hawliczek to carry out the experimental work.
These processes may be broadly divided into three classes:
(1.) Processes which propose to combine nascent hydrogen with
nitrogen at high temperatures or by electricity, with or without
the presence of acid gases.
(2.) Processes in which nitrides are first formed, from which
ammonia is obtained by the action of hydrogen or steam.
(3.) Processes in which cyanides are first formed and the ammonia
obtained from these by the action of steam.
We began with an investigation of those processes in which a mixture
of steam and nitrogen or of steam and air is made to act upon coke at
a high temperature, sometimes in the presence of lime, baryta, or an
alkali, sometimes in the presence of hydrochloric acid.
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