Scientific American Supplement, No. 717, September 28, 1889Various
Science
Scientific American Supplement, No. 717, September 28, 1889
Various
Science -- Periodicals
The process certainly also offers a solution of the problem of
obtaining ammonia from the nitrogen of the atmosphere, but whether
this can be done with satisfactory commercial results is a question I
cannot at present answer, as I have not been able to secure the data
for making the necessary calculations.
I am the more doubtful about this point, as in the course of our
investigations I have found means to produce ammonia at small cost and
in great abundance from the immense store of combined nitrogen which
we possess in our coal fields.
Among the processes for obtaining ammonia from the nitrogen of the air
which we investigated, was one apparently of great simplicity,
patented by Messrs. Rickman and Thompson. These gentlemen state that
by passing air and steam through a deep coal fire, the nitrogen so
passed through is to a certain extent converted into ammonia. In
investigating this statement we found that the process described
certainly yields a considerable quantity of ammonia, but when we
burned the same coal at a moderate temperature by means of steam
alone in a tube heated from the outside, we obtained twice as much
ammonia as we had done by burning it with a mixture of air and steam,
proving in this case, as in all others, the source of the ammonia to
have been the nitrogen contained in the coal. The quantity of ammonia
obtained was, however, so large that I determined to follow up this
experience, and at once commenced experiments on a semi-manufacturing
scale to ascertain whether they would lead to practical and economic
results.
I came to the conclusion that burning coal by steam alone at a
temperature at which the ammonia formed should not be dissociated,
although it yielded more ammonia, would not lead to an economic
process, because it would require apparatus heated from the outside,
of great complication, bulk, and costliness, on account of the immense
quantity of raw material to be treated for a small amount of ammonia
obtainable.
On the other hand, if the coal could be burned in gas producers by a
mixture of air and steam, the plant and working of it would be simple
and inexpensive, the gas obtained could be utilized in the same way as
ordinary producer gas, and would pay to a large extent for the coal
used in the operation, so that although only one-half of the ammonia
would be obtained, it seemed probable that the result would be
economical.
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