Scientific American Supplement, No. 810, July 11, 1891Various
Science
Scientific American Supplement, No. 810, July 11, 1891
Various
Science -- Periodicals
If we were not prepared to find so few really fast natural dyes,
surely we cannot but be surprised to find what a considerable number
of fast dyes are to be met with among the coal tar coloring matters
requiring the aid of mordants.
On these diagrams, the first vertical column shows the stain given by
the coloring matter alone; the remaining columns show the colors
obtained when the same coloring matters are applied in conjunction
with the several mordants--chromium, aluminum, tin, copper, and iron.
It was formerly held that the office of a mordant was merely to fix
the coloring matter upon the fiber; we now know, however, and it is
plainly illustrated by these diagrams, that this view is erroneous,
for the mordant not only fixes but also develops the color; the
mordant and coloring matter chemically combine with each other, and
the resultant compound represents the really useful pigment or dye. If
a coloring matter is combined with different mordants, the dyes thus
obtained represent distinct chemical products, and it is quite
natural, therefore, to find them differing from each other in color,
and their resistance toward light.
Knowing this, it is clearly the duty of the dyer to apply each
coloring matter of this class with a variety of mordants, and to
select the particular combination which gives him the desired color
and fastness. By adopting this method, however, his selection would
ultimately comprise a large number of coloring matters paired with a
great variety of mordants. In order, therefore, to avoid the intricacy
involved in the use of several mordants, and to simplify the process
of dyeing, especially when dyeing compound shades, the dyer prefers to
limit himself as far as possible to the use of a single mordant, and
to employ along with it a mixture of several coloring matters.
Now the woolen dyer has largely adopted an excellent mordant in
bichromate of potash; it is cheap, easily applied, and not perceptibly
injurious to the fiber. It is his desire, therefore, to have a good
range of red, yellow, blue, and other coloring matters, all giving
fast dyes with this mordant. This action and desire on the part of the
dyer has more and more placed the problem of producing fast colors
upon the shoulders of the color manufacturer or chemist, and right
well has the demand been met, for in the diagram on the wall we see
how, in the alizarin colors and their allies, he has already furnished
the dyer with a goodly number of dyestuffs yielding fast dyes with
this chosen mordant of the woolen dyer. Since, however, they yield
fast colors with other useful mordants, and upon other fibers than
wool, these alizarin colors prove of the greatest value to the dyer of
textile fabrics generally. Let us not forget the fact, then, that it
is among the "mordant dyes," the very class to which belong most of
the natural coloring matters, that we find our fastest coal tar dyes.
Public-domain text, read in full here on John Shaqi.
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