Scientific American Supplement, No. 810, July 11, 1891Various
Science
Scientific American Supplement, No. 810, July 11, 1891
Various
Science -- Periodicals
Among the "Congo oranges and yellows," we find some of the fastest on
cotton of this class of colors. Still they deserve only the rank of
medium fastness. They are Mikado orange 4 R, R, G. Hessian yellow,
curcumin S, chrysophenin. On wool, we have about half a dozen of
medium fastness, viz., benzo-orange, Congo orange R, chrysophenin G,
chrysamin R, brilliant yellow. On silk, however, we find in this group
about a dozen of the fastest oranges and yellows with which we are
acquainted for this fiber, viz., Congo orange R, chrysophenin G,
diamine yellow N, brilliant yellow, curcumin W, benzo orange, Hessian
yellow, chrysamin R and G, cresotin yellow R and G, cotton yellow G,
and carbazol yellow.
Does it not appear somewhat remarkable that we should find among this
generally fugitive group of coloring matters colors which are so
eminently fast on silk, and which we entirely fail to meet with among
those groups which usually furnish our fast colors, e.g., the alizarin
group?
Passing on to the "Congo violets, blues, and purples," we find few
colors worthy of particular notice for fastness. Diamine violet N
appears, perhaps, of medium fastness on wool and silk, while
sulphonazurin, benzo-black blue, and direct gray may claim the same
distinction on silk.
In the small group of colors which are produced directly upon the
fiber, none seems to call for special notice, except aniline black,
which, notwithstanding its direct derivation from aniline, is probably
the fastest color we have upon any fiber.
Now, in classifying the whole range of coal tar coloring matters into
"mordant dyes" and "direct dyes," and the latter into acid, basic,
Congo colors, etc., I have looked at them from the point of view of
the dyer and arranged them according to color and mode of application.
The chemist, however, classifies them quite differently, viz.,
according to their chemical constitution, i.e., the arrangement of the
atoms of which they are composed, and thus we have nitro colors,
phthaleins, azines, and so on.
In studying the action of light on the coal tar colors from this point
of view, we find that whereas the members of some groups are for the
most part fugitive, the members of other groups are nearly all fast,
and it becomes at once apparent that the chemical constitution of a
coloring matter exercises a profound influence upon its behavior
toward light. Members of the rosaniline group are all similarly
fugitive, while those of the alizarin group possess generally the
quality of fastness. Particularly fugitive are the eosins, and yet
some of these, by a slight modification of constitution, e.g., the
introduction of an ethyl group, as in ethyl-eosin, are rendered
distinctly faster.
In the azo group some colors are fugitive, others are moderately fast,
and it is generally recognized that certain classes of the tetrazo
compounds are distinctly faster than the ordinary diazo colors.
Public-domain text, read in full here on John Shaqi.
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