Scientific American Supplement No. 819, September 12, 1891Various
Science
Scientific American Supplement No. 819, September 12, 1891
Various
Science -- Periodicals
In the majority of refrigerating and ice machines ammonia gas is the
substance used for producing the refrigeration, although there are
other machines in which other material is employed, one of these being
anhydrous sulphurous acid, which is also a gas. Ammonia of itself is a
colorless gas, but little more than one half as heavy as air. In its
composition ammonia consists of two gases, nitrogen and hydrogen, in
the proportion by weight of one part nitrogen and three parts
hydrogen. The gas hydrogen is one of the constituents of water and is
highly inflammable in the presence of air or oxygen, while the other
component of ammonia, nitrogen, forms the bulk or about four-fifths of
the atmosphere. Nitrogen by itself is an inert gas, colorless and
uninflammable. Ammonia, although composed of more than three-fourths
its weight of hydrogen, is not inflammable in air, on account of its
combination with the nitrogen. This combination, it will be
understood, is not a simple mixture, but the two gases are chemically
combined, forming a new substance which has characteristics and
properties entirely different from either of the gases entering into
its composition when taken alone or when simply mixed together without
chemical combustion. Ammonia cannot be produced by the direct
combination of these elements, but it has been found that it is
sometimes made or produced in a very extraordinary manner, which goes
to show that there is yet considerable to be learned in regard to the
chemistry of ammonia. Animal or vegetable substances when putrefying
or suffering destructive distillation almost invariably give rise to
an abundant production of this substance.
The common method for the manufacture of ammonia is to produce it from
the salt known as sal-ammoniac. Sal-ammoniac as a crystal is obtained
in various ways, principally from the ammoniacal liquor of gas works,
also from the condensed products of the distillation of bones and
other animal refuse in the preparation of animal charcoal, and which
is of a highly alkaline nature. This liquid is then treated with a
slight excess of muriatic acid to neutralize the free alkali, and at
the same time the carbonates and sulphides are decomposed with the
evolution of carbonic acid and sulphureted hydrogen. All animal
matter, the meat, bones, etc., contain considerable carbon, while the
nitrogen from which the ammonia is produced forms a smaller portion of
the substance. The object is then to get rid of the carbon and
sulphur, leaving the nitrogen to combine, through chemical affinity,
with a portion of the hydrogen of the water, the oxygen which is set
free going to form the carbonic acid by combining with the carbon. The
liquor after being neutralized is evaporated to dryness, leaving a
crystallized salt containing a portion of tarry matter.
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