Scientific American Supplement No. 819, September 12, 1891Various
Science
Scientific American Supplement No. 819, September 12, 1891
Various
Science -- Periodicals
The salt is then purified by sublimation, that is, it is heated in a
closed iron vessel until it is transformed into a gas which separates
and leaves, in a carbonized state, all foreign substance. After this
gas is cooled, it condenses and again forms crystals which are in a
much purer condition. If necessary to further purify it, it is again
sublimed. The iron vessels in which the sublimation takes place are
lined with clay and covered with lead. The clay lining and lead
covering are necessary, for if the gas evolved during the process of
sublimation came in contact with the iron surface, the gas would be
contaminated and the iron corroded. Sublimed sal-ammoniac has a
fibrous texture and is tough and difficult to powder. It has a sharp,
salty taste and is soluble in two and a half parts of cold and in a
much smaller quantity of hot water. During the process of sublimation
the ammonia is not decomposed. But there are several ways in which the
gas may be decomposed, and a certain portion of it is decomposed in
the ordinary use of it in refrigerating machines. If electric sparks
are passed through the gas, it suffers decomposition, the nitrogen and
hydrogen then being in the condition of a simple mixture. When
decomposed in this manner, the volume of the gas is doubled and the
proportion is found to be three measures of hydrogen to one of
nitrogen, while the weight of the two constituents is in the
proportion of three parts hydrogen to fourteen of nitrogen.
The ammonia gas may also be decomposed by passing through a red hot
tube, and the presence of heated iron causes a slight degree of
decomposition. This sal-ammoniac is powdered and mixed with moist
slaked lime and then gently heated in a flask, when a large quantity
of gaseous ammonia is disengaged. The gas must be collected over
mercury or by displacement. The gas thus produced has a strong,
pungent odor, as can easily be determined by any one working around
the ammonia ice or refrigerating machines, for as our friend, Otto
Luhr, says, "It is the worst stuff I ever smelled in my life." The gas
is highly alkaline and combines readily with acids, completely
neutralizing them, and the aqua ammonia is one of the best substances
to put on a place burned by sulphuric acid, as has been learned by
those working with that substance, for although aqua ammonia of full
strength is highly corrosive and of itself will blister the flesh, yet
when used to neutralize the effect of a burn from sulphuric acid its
great affinity for the acid prevents it from injuring the skin under
such conditions.
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