Scientific American Supplement, No. 821, September 26, 1891Various
Science
Scientific American Supplement, No. 821, September 26, 1891
Various
Science -- Periodicals
------------+------+--------+-------------|
Temperature.| [eta]|Z found.|Z calculated.|
------------+------+--------+-------------|
°C. | | | |
50 |0.0430| 347 | 347 |
46 |0.0475| 383 | 371.14 |
42 |0.0502| 405 | 397.09 |
38 |0.0510| 411 | 424.73 |
34 |0.0575| 463 | 454.06 |
30 |0.0602| 485 | 485 |
26 |0.0637| 513 | 517.82 |
22 |0.0667| 538 | 552.25 |
20 |0.0707| 570 | 570 |
18 |0.0755| 609 | 583.07 |
------------+------+--------+-------------+
The constants for the first gum are those given in the preceding column,
while for the latter they were--
A = 771.9: B = -11.15: C = 0.053
As will be observed, the effect of heat appears to be the same upon the
two typical gum arabics quoted above, an increase of temperature from
18° C. to 50° C. decreasing the viscosity by nearly one half in both
cases, and the same seems to be true of most gum arabics. Roughly also
the same holds good for Ghattis, as the following numbers show:
------------+-------------+------------|
Gum. | Z at 18° C. | Z at 50° C.|
------------+-------------+------------|
Gum arabic. | 1016 | 579 |
Gum arabic. | 428 | 228 |
Gum arabic. | 609 | 347 |
Gum arabic. | 581 | 258 |
Ghatti. | 572 | 306 |
Ghatti. | 782 | 418 |
---------------------------------------+
The following table shows the effect of heat upon the viscosity of a
typical Ghatti:
GHATTI GUM NO. 15.--VISCOSITY.
------------+------+-----|
Temperature.| [eta]| Z. |
------------+------+-----|
°C. | | |
50 |0.0517| 418 |
46 |0.0581| 468 |
42 |0.0628| 506 |
38 |0.0726| 585 |
34 |0.0788| 635 |
30 |0.0857| 691 |
26 |0.0889| 717 |
22 |0.0919| 741 |
20 |0.0946| 763 |
18 |0.0964| 777 |
------------+------+-----+
There is therefore no essential difference in the behavior of a Ghatti
and a gum arabic on heating. Some interesting results, however, were
obtained by heating gums, both Ghattis and arabics, at a fixed
temperature for the same time, cooling, and then after making the
solutions up to the original volume taking their viscosities at the
ordinary temperature. The effect of heating for two hours to 60° C., 80°
C., or 100° C. was a small permanent alteration in viscosity of the
solution, and it would therefore seem desirable that gum solutions
should be made up cold to get the maximum results. The following numbers
illustrate this change, viz.:
Public-domain text, read in full here on John Shaqi.
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