Scientific American Supplement, No. 821, September 26, 1891Various
Science
Scientific American Supplement, No. 821, September 26, 1891
Various
Science -- Periodicals
From observation of the general nature of the solutions of Ghatti gums,
and from the fact that when allowed to stand portions of the apparently
insoluble matter passed into solution, the hypothesis suggested itself
that metarabin was soluble in arabin, although insoluble in cold water.
If this hypothesis were correct, it would explain the apparent anomaly
of Ghattis giving solutions of higher viscosity than gum arabics,
although they leave insoluble matter behind. The increase in viscosity
would be due to the thickening of the arabic acid by the metarabin.
Moreover, the solutions yielded by various Ghattis leaving insoluble
matter behind would _be all of the same kind_, viz., a saturated
solution of metarabin in arabin more or less diluted by water. Still
further, if the insoluble residue of a Ghatti be the residual metarabin
over and above that required to saturate the arabin, then it will be
possible to dissolve this by the addition of more arabin in the form of
ordinary gum arabic. In order to see if this were the case the following
experiments were performed. Equal parts of a Ghatti and of a gum arabic
were ground up together and dissolved in water. The resulting solution
was _clear_. It was diluted until of 10 per cent. strength, and its
viscosity then taken:
---------------------+-------------+----------------+
| Contains 50 per Cent. Ghatti.|
---------------------+-------------+----------------+
A. Pressure 200 mm | [eta] | Z. |
Temperature 15° C | 0.2517 | 2,030 |
---------------------+-------------+----------------+
The viscosity of this solution therefore was considerably greater than
the mean viscosity of the 10 per cent. solutions of the Ghatti and the
gum arabic, viz., (0.288 + 0.0636)/2 = 0.1758 for the calculated [eta].
Hence it is evident that the increase in viscosity is due to the
solution of the metarabin.
Next a solution was made from a mixture of 70 per cent. Ghatti and 30
per cent. gum arabic. This was also clear and gave a considerably higher
viscosity than the previous solution.
---------------------+------------------------------+
| Contains 70 per Cent. Ghatti.|
---------------------+-------------+----------------+
B. Pressure 200 mm | [eta] | Z. |
Temperature 15° C | 0.3177 | 2,562 |
---------------------+-------------+----------------+
It will be obvious that the increase of viscosity over the previous
solution in this case must be due to the smaller amount of the thin gum
arabic which is present, _i.e._, in the first case there is more gum
arabic than is required to dissolve the whole of the insoluble
metarabin. Further experiments showed that this is also true of the
second mixture, as the viscosities of the following mixtures
illustrate:
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