Scientific American Supplement, No. 821, September 26, 1891Various
Science
Scientific American Supplement, No. 821, September 26, 1891
Various
Science -- Periodicals
----------------+----------------+-----------------
Gum or Dextrin. | Solution used. | [alpha]_{D}
----------------+----------------+-----------------
| Per Cent. |
Aden, 1 | 5 | - 33.8
Cape, 2 | 5 | + 28.6
Indian, 3 | 5 | + 66.2
Eastern, 4 | 5 | - 26.0
Eastern, 5 | 5 | - 30.6
Senegal, 6 | 5 | - 17.6
Senegal, 7 | 5 | - 18.4
Senegal, 8 | 2½ | - 19.6
Senegal, 9 | 5 | - 38.2
Senegal, 10 | 5 | - 25.8
Amrad | 2½ | + 57.6
Australian, 1 | 5 | - 28.2
Australian, 2 | 5 | - 26.4
Brazilian, 1 | 2½ | - 36.8
Brazilian, 2 | 2½ | + 21.0
Dextrin, 1 | 5 | +148.0
Dextrin, 2 | 5 | +133.2
Ghatti, 1 | 5 | - 39.2
Ghatti, 2 | 5 | - 80.4
----------------+----------------+-----------------
These numbers do not show any marked connection between the viscosity,
etc., of a gum and its specific rotatory power.
When gum arabic solution is treated with alcohol the gum is precipitated
entirely if a large excess of spirit be used. With a view to seeing if
the precipitate yielded by the partial precipitation of a gum solution
was identical in properties to the original gum, we examined several
such precipitates from various gums to ascertain their rotatory power.
We found in each case that the specific rotatory power of the alcohol
precipitate redissolved in water was not the same as that of the
original gum. In other words these gums contained at least two bodies of
different rotatory powers, of which one is more soluble in alcohol than
the other. O'Sullivan obtained similar results with pure arabin. The
experiments were conducted in the following manner:
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