Scientific American Supplement, No. 829, November 21, 1891Various
Science
Scientific American Supplement, No. 829, November 21, 1891
Various
Science -- Periodicals
1, 2, 3, 4, 5 equivs. of carbonate of lime with
1, 2, 3, 4, 5 " sulphurous acid and
3, 5, 7, 9, 11 " sulphureted hydrogen.
Thus we find that:
Carbonate of lime, 2CaCO_{3}, } { 2(CaSO.H_{2}O) (gypsum),
Sulphurous acid, 2SO_{2}, and } yield { 4S (sulphur), and
Sulphureted hydrogen, 4H_{2}S, } { C_{2}H_{4}, which is
{ _ethylene_.
And that:
Carbonate of lime, CaCO_{3} } { (CaSO_{4}.H_{2}O) (gypsum),
Sulphurous acid, SO_{2}, and } yield { 3S (sulphur) and
Sulphureted hydrogen, 3H_{2}S, } { CH4, which is marsh gas.
So that these and all their homologues, in fact petroleum in all its
varieties, would be produced in nature by the action of volcanic gases
on limestone.
But much the most abundant of the volcanic gases appear at the surface
as steam, and petroleum seems to have been more usually produced
without sulphurous acid, and with part of the sulphureted hydrogen
(H_{2}S) replaced by H_{2}O (steam) or H_{2}O_{2} (peroxide of
hydrogen), which is the product that results from the combination of
sulphureted hydrogen and sulphurous acid:
(H_{2}S + SO_{2} == H_{2}O_{2} + 2S).
It is a powerful oxidizing agent, and it converts sulphurous into
sulphuric acid. Thus:
CaCO_{3} } { CaSO_{4}.H_{2}O (gypsum)
H_{2}S, } yield { and
2H_{2}O, } { CH_{4}, which is marsh gas.
And
2CaCO_{3}, } { 2CaSO_{4}.H_{2}O
2H_{2}S, } yield { and
2H_{2}O_{2}, } { C_{2}H_{4}, which is _ethylene._
Tables are given showing the formulae for the homologues of ethylene
and marsh gas resulting from the increase in regular gradation of the
same constituents.
_Formulae Showing how Ethylene and its Homologues
(C_{n}H_{2}{n}) are Produced by the Action of the Volcanic
Gases H_{2}S and H_{2}O_{2} on Limestone._
Carbonate Sulphureted Peroxide of Ethylene and
of lime. hydrogen. hydrogen. Gypsum. its homologues.
Public-domain text, read in full here on John Shaqi.
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