Scientific American, Vol. XXXIX.—No. 24. [New Series.], December 14, 1878: A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and ManufacturesVarious
Science
Scientific American, Vol. XXXIX.—No. 24. [New Series.], December 14, 1878: A Weekly Journal of Practical Information, Art, Science, Mechanics, Chemistry, and Manufactures
Various
Science -- Periodicals; Technology -- Periodicals
It is well known that the efficient preservation of iron against
rusting is at present only provided for in cases where human life
would be endangered by failure, as in the case of railway bridges
and steamers. Thus, for example, at Mr. Cramer-Klett's ironworks at
Nuremberg every piece of iron used for his bowstring bridges is dipped
in oil heated to eight hundred degrees. The very great care which
is at present taken in this matter may be judged from the current
practice of most bridge and roofing manufacturers. Every piece of
iron before being riveted in its place is cleaned from rust by being
immersed in a solution of hydrochloric acid. The last traces of free
acid having been cleared away, at first by quicklime and afterward by
a copious ablution with hot water, the piece is immediately immersed
in hot linseed oil, which protects every part of the surface from the
action of the atmosphere. Afterward it is riveted and painted.
Notwithstanding all this, the painting requires continual and
careful renewal. On the Britannia Bridge, near Bangor, the painter is
permanently at work; yet, in spite of all this care and expense, rust
cannot be entirely avoided. The age of iron railway bridges is still
too short to enable us to draw conclusions as to the probabilities of
accidents. Now, Professor Barff has discovered a process by which
iron may be kept from rusting by being entirely coated with its own
sesquioxide. A piece of iron exposed to the action of superheated
steam, in a close chamber and under a certain pressure, becomes
gradually covered by a skin of this black oxide, of a thickness
depending upon the temperature of the steam and the duration of
the experiment. For instance, exposure during five hours to steam
superheated to five hundred degrees will produce a hermetical coating
capable of resisting for a considerable time the application of emery
paper and of preserving the iron from rust even in a humid atmosphere,
if under shelter from the weather. If the temperature is raised to
1,200 degrees, and the time of exposure to six or seven hours, the
skin of sesquioxide will resist every mechanical action, and the
influence of any kind of weather. The sesquioxide being harder than
the iron itself, and adhering to its surface even more firmly than the
atoms of iron do to each other, there is an increased resistance not
only to chemical but also to mechanical action. The surface is not
altered by the process in any other respect, a plain forging retaining
its roughness, a polished piece its smooth surface. If the skin is
broken away oxidation takes place, but only just on the spot from
which the oxide has been removed. If Professor Barff's experiments
are borne out by practice, this invention may become of very great
importance. It is within the bounds of probability that it may enable
iron, by increasing its facility in competing with wood, to recover,
at least for a considerable time, even more than the ground it has
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account