Scientific American, Volume 56, No. 9, February 26, 1887Various
Science
Scientific American, Volume 56, No. 9, February 26, 1887
Various
Science -- Periodicals; Technology -- Periodicals
It is not the purpose of this article to enter into a lengthy
discussion of Mr. Castner' process of producing sodium, as Mr. James
Mactear, F.C.S., is about to prepare a scientific paper on the subject,
to be read on March 7 before the Society of Chemical Industry. We
shall content ourselves by presenting to our readers a short practical
description of the process and its results.
Before doing so it will, however, be advantageous to give a short
account of the method by which sodium has hitherto been separated from
its compounds, in order that a clearer conception of the features in
which the new process differs from the old one may be obtained. At
high temperatures carbon has the property of separating sodium from
its oxygen compounds, carbon uniting with the oxygen to form carbonic
oxide, the sodium being thereby liberated. In the usual process this
reaction is brought about by mixing carbonate of soda, lime, and carbon
in small wrought iron cylinders, and exposing them to an intense heat,
when a part of the sodium comes off as vapor. The lime is added to
prevent fusion, for were the mass to melt, the carbon would float on
the top, and could no longer attack the soda. The new process differs
from the old principally in working with a fused mass of soda compound,
this operation having been rendered feasible by the most ingenious
device of weighting every particle of carbon with iron, so that the
two chemicals--soda and carbon--are kept in perfect admixture, and
are continually presenting fresh surfaces to each other as the liquid
circulates in the crucible under the action of the heat. By this simple
but beautiful plan of weighting the carbon, it is rendered possible to
employ a soda compound which is decomposed at a much lower temperature
than that hitherto used, and to carry on the process in large and
durable vessels, instead of in small cylinders, which have a very short
life. Having thus given a short account of the chemical process, we
will describe the commercial method of manufacture.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account