Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
By the second investigation, as by the first, although Dumas gave a most
fruitful conception to chemistry, he only took the first step in
developing it. His conception of chemical types was very indefinite, and
Laurent wrote of it, a few years later: "Dumas's theory is too general;
by its poetic coloring, it lends itself to false interpretations; it is
a programme of which we await the realization." Laurent himself helped
toward this realization, and in his early death left the work to his
associate and friend Gerhardt, who pushed it forward with great zeal,
classifying chemical compounds according to the four types of
hydrochloric acid, water, ammonia, and marsh-gas. Hofmann, Williamson,
Wurtz, and many others, greatly aided in this work by realizing many of
the possibilities which these types suggested; and thus modern
Structural Chemistry gradually grew up, in which the types of Dumas and
Gerhardt have been in their turn superseded by the larger views which
the doctrine of quantivalence has opened out to the scientific
imagination. It is a singular fact, however, that, while the growth
began in France, the harvest has been chiefly reaped by Germans; and
that, although in its inception the movement was strongly opposed in
Germany, its legitimate conclusions are now repudiated by the most
influential school of French chemists.
The third great investigation of Dumas was his revision of the atomic
weights of many of the chemical elements, and in none of his work did
he show greater experimental skill. His determination of the atomic
weight of oxygen by the synthesis of water, and of that of carbon by the
synthesis of carbonic dioxide, are models of quantitative experimental
work. To this investigation, as to all his other work, Dumas was
directed by his vivid scientific imagination. In his teaching, from the
first, he had aimed to exhibit the relations of the elementary
substances by classing them in groups of allied bodies; and at the
meeting of the British Association in 1851 he had delighted the chemical
section by the eloquence and force with which he exhibited such
relations, especially triads of elementary substances; such as chlorine,
bromine, and iodine; oxygen, sulphur, and selenium; phosphorus, arsenic,
and antimony; calcium, barium, and strontium: in which not only the
atomic weight, but also the qualities of the middle member of the triad,
were the mean of those of the other two members. Later, he came to
regard these triads as parts of more extended series, in each of which
the atomic weights increased from the first to the last element of the
series, by determinate, but not always by equal differences, the values
being, if not exact multiples of the hydrogen atom according to the
hypothesis of Prout, at least multiples of one half or one quarter of
that weight. There can be no doubt that these speculations were more
fanciful than sound, and that Dumas did not do full justice to earlier
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