Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
The second law declares that in every chemical process the weights of
the several factors and products bear each to the others a definite
proportion. This law must next be made familiar by experimental
illustrations. A weighed amount of oxide of silver is placed in a glass
tube connected with a pneumatic trough. The tube is gently heated until
the oxide is decomposed and the oxygen gas collected in a glass bottle
of sufficient size. The metallic silver remaining in the tube is now
reweighed, and the volume of the oxygen gas in the bottle measured, and
from the volume of the gas its weight is deduced. The measurement is
easily made by simply marking with a gummed label the level at which the
water stands in the bottle. If, now, the bottle is removed from the
pneumatic trough and the weight of water found which fills the bottle to
the same height, the weight of the water in grammes will give the volume
of the gas in cubic centimetres, and, knowing the weight of a cubic
centimetre of oxygen, we easily calculate the weight of this gas
resulting from the chemical process. We have now the weights of the
oxide of silver, the silver, and the oxygen, the one factor and the two
products of the chemical process, and, by comparing the results of
different students making the same experiment, the constancy of the
proportion will be made evident to the class.
For a second illustration of the same law, the solution of zinc in
dilute sulphuric acid, yielding sulphate of zinc and hydrogen gas, may
be selected, and the weight of the hydrogen, estimated as in the
previous example, shown to sustain a definite relation to the weight of
the zinc dissolved.
Again, silver may be dissolved in nitric acid, and the weight of the
nitrate of silver obtained shown to sustain a definite relation to the
weight of the metal.
Or, still further, as an experiment of a wholly different class, a known
weight of chloride of barium may be dissolved in water, and, after
precipitation with sulphuric acid, the baric sulphate collected by
filtration and weighed, when the definite relation between the weight of
the precipitate and the weight of the chloride of barium will appear.
Public-domain text, read in full here on John Shaqi.
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