Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
For a last experiment let the student neutralize a weighed amount of
dilute hydrochloric acid with aqua ammonia, noting approximately the
amount of ammonia required. Let him now evaporate the solution on a
water-bath, and weigh the resulting saline product; taking next the same
quantity of hydrochloric acid as before, and, having added twice the
previous quantity of ammonia, let him obtain and weigh the resulting
salammoniac as before. A third time let him begin with half the
quantity of hydrochloric acid, and, adding as much ammonia as in the
first case, again repeat the process. It is obvious what the result of
these experiments must be; but without telling the student what he is to
expect, it will be a good exercise to ask him to draw his own inferences
from the results. Of course, he must previously have so far been made
acquainted with the properties of hydrochloric acid and ammonia as to
know that the excess of either would escape when the saline solution is
evaporated over a water-bath. But with this limited knowledge he will be
able to deduce the law of definite proportions from the experimental
results thus simply obtained.
The third of the fundamental laws of chemistry stated above (generally
known as the law of Gay-Lussac) declares that, when two or more of the
factors or products of a chemical process are aeriform, the volumes of
these gaseous substances bear to each other a very simple ratio. Here,
again, numerous experiments may be contrived to illustrate the law.
Water, when decomposed by electricity, yields hydrogen and oxygen gases
whose volumes bear to each other the ratio of two to one. When
hydrochloric-acid gas is decomposed by sodium amalgam, the volume of the
original gas bears to that of the residual hydrogen the ratio also of
two to one. When ammonia is decomposed by chlorine, the volume of the
resulting nitrogen gas is one third of that of the chlorine gas
employed.
Having illustrated these three general laws, attention should be
directed to the fact that the nature of a chemical process and the laws
which it obeys are results of observation and involve no theory
whatsoever. On these facts the science of chemistry is built. The modern
system of chemistry, however, assumes what is known as the molecular
theory, and by means of this theory attempts to explain all these facts
and show their mutual relations. Here the distinction between fact and
theory must be insisted upon, and also the value of theory for
classifying facts and directing observation.
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