Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
A molecule is now defined, and, if the student has not studied physics
sufficiently to become acquainted with the outlines of the kinetic
theory of gases, this theory must be developed sufficiently to give the
student a knowledge of the three great laws of Mariotte, of Charles, and
of Avogadro. He must be made to understand how molecules are defined by
the physicist, and how their relative weights may be inferred by a
comparison of vapor densities. He should then be made to compare the
relative molecular weights, deduced by physical means, with the definite
proportions he has observed in chemical processes. He will thus himself
be led to the conclusion that these definite proportions are the
proportions of the molecular weights, and that the constancy of the law
arises from the fact that in every chemical process the action takes
place between molecules, and that the products of the process are new
molecules, preserving always, of course, their definite relative
weights. The student will thus be brought to the chemical conception of
the molecule as the smallest mass of any substance in which the
qualities inhere, and he will come to regard a chemical process as
always taking place between molecules.
Thus far nothing has been said about the composition of matter. A
chemical process has been defined simply as certain factors yielding
certain products, but nothing has been determined about the relations of
these several substances except in so far as they are defined by the
three laws illustrated above. But now it must be shown that a study of
different chemical processes compels us to conclude that in some cases
two or more substances unite to form a compound, while in other cases a
compound is broken up into simpler parts. Thus, when copper-filings are
heated in the air, it is evident that the material of the copper has
united with that portion of the air we call oxygen to form the black
product we call oxide of copper; and again, when oxide of silver is
heated, it is evident that the resulting silver and oxygen gas were
formerly portions of the material of the oxide. So, when water is
decomposed by electricity, the conditions of the experiment show that
the resulting oxygen and hydrogen gases must have come from the material
of the water, and could have come from nothing else.
Experiments should now be multiplied until the student has a perfectly
clear idea of the nature of the evidence on which our knowledge of the
composition of bodies depends. The decomposition of chlorate of potash
by heat, yielding chloride of potassium and oxygen gas; the
decomposition of nitrate of ammonium by heat, yielding nitrous oxide and
water; the decomposition of this resulting nitrous oxide, when the gas
is passed over heated metallic copper; and, lastly, the decomposition
already referred to, of water by electricity--are all striking
experiments by which the evidence of chemical composition may be
enforced.
Public-domain text, read in full here on John Shaqi.
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