Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
One of the most remarkable results of Graham's study of this peculiar
mode of transfer of aeriform matter through the very substance of solid
bodies was an ingenious method of separating the oxygen from the
atmosphere. The apparatus consisted simply of a bag of India-rubber kept
distended by an interior framework, while it was exhausted by a Sprengel
pump. Under these circumstances the selective affinity of the caoutchouc
determines such a difference in the rate of transfer of the two
constituents of the atmosphere that the amount of oxygen in the
transpired air rises to forty per cent., and by repeating the process
nearly pure oxygen may be obtained. It was at first hoped that this
method might find a valuable application in the arts, but in this Graham
was disappointed; for the same result has since been effected by purely
chemical methods, which are both cheaper and more rapid.
These experiments on India-rubber naturally led to the study of similar
effects produced with metallic septa, which, although to some extent
previously observed in passing gases through heated metallic tubes, had
been only imperfectly understood. Thus, when a stream of hydrogen or
carbonic oxide is passed through a red-hot iron tube, a no
inconsiderable portion of the gas escapes through the walls. The same is
true to a still greater degree when hydrogen is passed through a red-hot
tube of platinum, and Graham showed that, through the walls of a tube
of palladium, hydrogen gas passes, under the same conditions, almost as
rapidly as water through a sieve. Moreover, our distinguished associate
proved that this rapid transfer of gas through these dense metallic
septa was due, as in the case of the India-rubber, to an actual chemical
combination of its material with the metal, formed at the surface, where
the gas is in excess, and as rapidly decomposed on the opposite face of
the septum. He not only recognized as belonging to this class of
phenomena the very great absorption of hydrogen by platinum plate and
sponge in the familiar experiment of the Doebereiner lamp, but also
showed that this gas is a definite constituent of meteoric iron--a fact
of great interest from its bearing on the meteoric theory.
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