Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
We are thus led to Graham's last important discovery, which was the
justification of the theory we have been considering, and the crowning
of this long line of investigation. As may be anticipated from what has
been said, the most marked example of that order of chemical compounds,
to which the metallic transpiration of aeriform matter we have been
considering is due, is the compound of palladium with hydrogen. Graham
showed that, when a plate of this metal is made the negative pole in the
electrolysis of water, it absorbs nearly one thousand times its volume
of hydrogen gas--a quantity approximatively equivalent to one atom of
hydrogen to each atom of palladium. He further showed that the metal
thus becomes so profoundly altered as to indicate that the product of
this union is a definite compound. Not only is the volume of the metal
increased, but its tenacity and conducting power for electricity are
diminished, and it acquires a slight susceptibility to magnetism, which
the pure metal does not possess. The chemical qualities of this product
are also remarkable. It precipitates mercury from a solution of its
chloride, and in general acts as a strong reducing agent. Exposed to the
action of chlorine, bromine, or iodine, the hydrogen leaves the
palladium and enters into direct union with these elements. Moreover,
although the compound is readily decomposed by heat, the gas can not be
expelled from the metal by simple mechanical means.
These facts recall the similar relations frequently observed between the
qualities of an alloy and those of the constituent metals, and suggest
the inference made by Graham, that palladium charged with hydrogen is a
compound of the same class--a conclusion which harmonizes with the
theory long held by many chemists, that hydrogen gas is the vapor of a
very volatile metal. This element, however, when combined with
palladium, is in a peculiarly active state, which sustains somewhat the
same relation to the familiar gas that ozone bears to ordinary oxygen.
Hence Graham distinguished this condition of hydrogen by the term
"hydrogenium." Shortly before his death a medal was struck at the Royal
Mint from the hydrogen palladium alloy in honor of its discovery; but,
although this discovery attracted public attention chiefly on account of
the singular chemical relations of hydrogen, which it brought so
prominently to notice, it will be remembered in the history of science
rather as the beautiful termination of a life-long investigation, of
which the medal was the appropriate seal.
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