Scientific Culture, and Other Essays: Second Edition; with AdditionsCooke, Josiah P., Jr. (Josiah Parsons)
Science
Scientific Culture, and Other Essays: Second Edition; with Additions
Cooke, Josiah P., Jr. (Josiah Parsons)
Science
Simultaneously with the experiments on _gases_, whose results we have
endeavored to present in the preceding pages, Graham carried forward a
parallel line of investigation of an allied class of phenomena, which
may be regarded as the manifestations of molecular motion in _liquid_
bodies. The phenomena of diffusion reappear in liquids, and Graham
carefully observed the times in which equal weights of various salts
dissolved in water diffused from an open-mouth bottle into a large
volume of pure water, in which the bottle was immersed. He was not,
however, able to correlate the results of these experiments by such a
simple law as that which obtains with gases. It appeared, nevertheless,
that the rate of diffusion differs very greatly for the different
soluble salts, having some relation to the chemical composition of the
salt which he was unable to discover. But he found it possible to divide
the salts into groups of equi-diffusive substances, and he showed that
the rate of diffusion of the several groups bear to one another simple
numerical ratios.
More important results were obtained from the study of a class of
phenomena corresponding to the transpiration of gases through
India-rubber or metallic septa. These phenomena, as manifested in the
transfer of liquids and of salts in solution through bladder or a
similar membrane, had previously been frequently studied under the names
of exosmose and endosmose, but to Graham we owe the first satisfactory
explanation. As in the case of gases, he referred these effects to the
influence of chemical force, combination taking place on one surface of
the membrane and the compound breaking up on the other, the difference
depending, as in the previous instance, on the influence of mass. He
also swept away the arbitrary distinctions made by previous
experimenters, showed that this whole class of phenomena are essentially
similar, and called this manifestation of power simply "osmose."
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