Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
DESCRIPTION--The Standard F. A. C. Vacuum Oven has been designed with
the idea of affording a simple and compact vacuum oven which will give
as uniform temperatures as possible on the shelf. As the figure shows,
it consists of an iron casting of rectangular sections with hinged front
door made tight by means of a gasket and which can be lowered on opening
the oven so as to form a shelf on which samples may be rested. The oven
contains but one shelf which is heated from above as well as below by
means of resistance coils. Several thermometer holes are provided in
order to ascertain definitely the temperature at different points on the
shelf. In a vacuum oven where the heating is done almost entirely by
radiation it is difficult to maintain uniform temperatures at all
points, but the F. A. C. oven accomplishes this rather better than most
vacuum ovens. Larger ovens containing more than one shelf have been
tried by the Committee, but have been found to be lacking in temperature
uniformity and means of control. The entire oven is supported by means
of a 4-in. standard pipe which screws into the base of the oven and
which in turn is supported by being screwed into a blind flange of
suitable diameter which rests on the floor or work table.
_Moisture Dish_--A shallow, glass dish, lipped, beaker form,
approximately 6 to 7 cm. diameter and 4 cm. deep, shall be standard.
DETERMINATION--Weigh out 5 grams (= 0.2 g. of the prepared sample) into
a moisture dish. Dry to constant weight in _vacuo_ at a uniform
temperature, not less than 15deg. C. nor more than 20deg. C. above the
boiling point of water at the working pressure, which must not exceed
100 mm. of mercury.[25] Constant weight is attained when successive
dryings for 1-hr. periods show an additional loss of not more that 0.05
per cent. Report loss in weight as MOISTURE AND VOLATILE MATTER.[26]
[Illustration: STANDARD VACUUM OVEN]
The vacuum-oven method cannot be considered accurate in the case of fats
of the coconut oil group containing free acid and the Committee
recommends that it be used only for oils of this group when they contain
less than 1 per cent free acid. In the case of oils of this group
containing more than 1 per cent free acid, recourse should be had
temporarily to the routine control method for moisture and volatile
matter[27] until the Committee develops a more satisfactory method.
The air-oven method cannot be considered even approximately accurate in
the case of the drying and semi-drying oils and those of the coconut oil
group. Therefore, in the case of such oils as cottonseed oil, maize oil
(corn oil), soy bean oil, linseed oil, coconut oil, palm kernel oil,
etc., the vacuum-oven method should always be used, except in the case
of fats of the coconut group containing more than 1 per cent free acid,
as noted above.
INSOLUBLE IMPURITIES.
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