Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
This determination, the title for which was adopted after careful
consideration, determines the impurities which have generally been known
as dirt, suspended matter, suspended solids, foreign solids, foreign
matter, etc., in the past. The first solvent recommended by the
committee is hot kerosene to be followed by petroleum ether kept at
ordinary room temperature. Petroleum ether, cold or only slightly warm,
is not a good fat and metallic soap solvent, whereas hot kerosene
dissolves these substances readily, and for this reason the committee
has recommended the double solvent method so as to exclude metallic
soaps which are determined below as soluble mineral matter.
SOLUBLE MINERAL MATTER.
Soluble mineral matter represents mineral matter combined with fatty
acids in the form of soaps in solution in the fat or oil. Formerly, this
mineral matter was often determined in combination by weighing the
separated metallic soap or by weighing it in conjunction with the
insoluble impurities. Since the soaps present consist mostly of lime
soap, it has been customary to calculate the lime present therein by
taking 0.1 the weight of the total metallic soaps. The standard method
as given above is direct and involves no calculation. The routine method
given in the note has been placed among the methods for the reason that
it is used in some laboratories, but has not been adopted as a standard
method in view of the fact that the committee has made it a rule to
adopt only one standard method. It should be pointed out, however, that
the method cannot be considered accurate for the reason that insoluble
impurities may vary from sample to sample to a considerable extent and
the error due to the presence of large particles of insoluble impurities
is thus transferred to the soluble mineral matter. The committee has
found one type of grease (naphtha bone grease) which shows most unusual
characteristics. The type sample contains 4.3 per cent soluble mineral
matter by the committee method which would be equivalent to 43.0 per
cent free fatty acid. The kerosene and gasoline filtrate was
particularly clear, nevertheless the ash was found to contain 36.43 per
cent P_{2}O_{5} equivalent to 79.60 per cent of Ca_{3}(PO_{4})_{2} and
9.63 per cent of Fe_{2}O_{3}. The method, therefore, determines the
soluble mineral matter in this case satisfactorily but the factor 10 is
not applicable for calculating the fatty acids combined therewith. It is
necessary, therefore, in order to determine the fatty acids combined
with soluble mineral matter in the original sample to determine the
actual bases in the soluble mineral matter as obtained by ashing the
kerosene and gasoline filtrate. To the bases so determined the factor 10
can then be applied.
FREE FATTY ACID.
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