Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
A melting point is the temperature at which a solid substance assumes
the liquid condition. If the solid is a pure substance in the
crystalline condition the melting point is sharp and well defined for
any given pressure. With increased pressure the melting point is lowered
or raised, depending on whether the substance contracts or expands in
melting. The lowering or raising of the melting point with pressure is
very slight and ordinarily is not taken into consideration.
Melting-point determinations are commonly carried out under ordinary
atmospheric pressures without correction. The general effect of soluble
impurities is to lower the melting point, and this holds true whether
the impurity has a higher or lower melting point than the pure substance
(solvent). Thus if a small amount of stearic acid be added to liquid
palmitic acid and the solution frozen, the melting point of this solid
will be lower than that of palmitic acid. Likewise the melting point of
stearic acid is lowered by the addition of a small amount of palmitic
acid. A eutectic mixture results when two components solidify
simultaneously at a definite temperature. Such a mixture has a constant
melting point and because of this and also because both solid and liquid
phases have the same composition, eutectic mixtures were formerly looked
upon as compounds. The phenomenon of double melting points has been
observed in the case of a number of glycerides. Such a glyceride when
placed in the usual capillary tube and subjected to increasing
temperature quickly resolidifies only to melt again and remain melted at
a still higher temperature. This phenomenon has not yet been
sufficiently investigated to afford a satisfactory explanation.
Non-crystalline substances such as glass, sealing wax and various other
waxes and wax mixtures, and most colloidal substances do not exhibit a
sharp melting point, but under the application of heat first soften very
gradually and at a considerably higher temperature melt sufficiently to
flow. This phenomenon of melting through a long range of temperature may
be due to the amorphous nature of the substance or to the fact that it
consists of a very large number of components of many different melting
points.
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