Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The fats and oils of natural origin, that is, the animal and vegetable
fats and oils, consist of mixtures of glycerides and, generally
speaking, of a considerable number of such components. These components
are crystalline and when separated in the pure state have definite
melting points, although some exhibit the phenomenon of double melting
point. For the most part the naturally occurring glycerides are mixed
glycerides. In the natural fats and oils there are present also certain
higher alcohols, of which cholesterol is characteristic of the animal
fats and oils and phytosterol of many of the vegetable fats and oils. In
addition to the crystalline glycerides and the higher alcohols present
in neutral fats, there are in fats of lower grade, fatty acids, which
are crystalline, and also various non-crystalline impurities of an
unsaponifiable nature, and the presence of these impurities tends to
lower the melting point. They also tend to induce undercooling and when
the liquid fat or oil is being chilled for purposes of solidification or
in determination of titer.
The presence of water, especially when this is thoroughly mixed or
emulsified with a fat or oil, also influences the melting point to a
marked extent, causing the mixture to melt through a longer range of
temperatures than would be the case if the water were absent. This is
particularly true of emulsified fats and oils, such as butter and
oleomargarine, both of which contain, besides water, the solids
naturally present in milk or cream and including casein, milk sugar, and
salts. The melting-point method recommended by the Committee is not
applicable to such emulsions or other watery mixtures and the Committee
has found it impossible to devise an accurate method for making
softening-point or melting-point determinations on products of this
nature. Not only the amount of water present but also the fineness of
its particles, that is, its state of subdivision and distribution, in a
fat or oil influences the softening point or melting point and causes it
to vary widely in different samples.
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