Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
As a consequence of the foregoing facts, natural fats and oils do not
exhibit a definite melting point, composed as they are of mixtures of
various crystalline glycerides, higher alcohols, fatty acids, and
non-crystalline substances. Therefore, the term melting point when
applied to them requires further definition. They exhibit first a lower
melting point (the melting point of the lowest melting component) or
what might be called the softening point and following this the fat
softens through a shorter or longer range of temperature to the final
melting point at which temperature the fat is entirely liquid. This is
the melting point determined by the Committee's melting-point method.
The range between the softening point and the final melting point varies
greatly with the different fats and oils depending on their chemical
components, the water associated with them, emulsification, etc. In the
case of coconut oil the range between softening point and final melting
point is rather short; in the case of butter, long. Various methods have
been devised to determine the so-called melting point of fats and oils.
Most of these methods, however, determine, not the melting point, but
the softening point or the flow point of the fat and the great
difficulty has been in the past to devise a method which would determine
even this point with reasonable accuracy and so that results could be
easily duplicated. It has been the aim of the Committee to devise a
simple method for the determination of the melting point of fats and
oils, but it should be understood that the term melting point in the
scientific sense is not applicable to natural fats and oils.
FOOTNOTES:
[22] Approved by the Supervisory Committee on Standard Methods of
Analysis of the American Chemical Society.
[23] Live steam must not be turned into tank cars or coils before
samples are drawn, since there is no certain way of telling when coils
are free from leaks.
[24] If there is water present under the solid material this must be
noted and estimated separately.
[25] Boiling point of water at reduced pressures.
Pressure Boiling Point Boiling Point Boiling Point
Mm. Hg. to 1deg. C. +15deg. C. +20deg. C.
100 52deg. C. 67deg. C. 72deg. C.
90 50 65 70
80 47 62 67
70 45 60 65
60 42 57 62
50 38 53 58
40 34 49 54
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