Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
The soap is now ready for finishing and is first boiled through and
tried for strength. A drop of phenolphthalein (1 per cent.
phenolphthalein in 98 per cent. alcohol) is allowed to drop on the
molten soap taken up on a trowel. The red color should be instantly
produced and develop to a full deep crimson in a few seconds, or more
lye must be added until this condition is realized. Should it flash a
deep crimson immediately it is on the strong side. This cannot be
conveniently remedied; it can only serve as a guide for the next boil,
but in any case it is not of any serious consequence, unless it is too
strong.
With the steam on, the soap is now examined with a trowel which must be
thoroughly heated by working it about under the surface of the hot soap.
The appearance of the soap as it runs from the face of the trowel
indicates its condition. It is not possible to absolutely describe the
effect, which can only be properly judged by practice, yet the following
points may serve as a guide. The indications to be noticed are the shape
and size of the flakes of soap as the sample on the trowel breaks up and
runs from the hot iron surface, when the latter is turned in a vertical
position, as well as the condition of the iron surface from which the
soap flakes have fallen. A closed soap will run slowly into a
homogeneous sheet, leaving the trowel's surface covered with a thin
layer of transparent soap; a grained mass will run rapidly down in tiny
grains, about one-half an inch in diameter or less, leaving the hot
trowel absolutely dry. The object of the finish is to separate the
soaps of the lower fatty acids from those of the higher, and both from
excess of liquid. A point midway between "open" and "closed" is required
to arrive at this point.
Having arrived at the above condition, the soap is allowed to settle
anywhere from one to three days and then run off through the skimmer
pipes to the nigre and framed or pumped to the tank feeding the drying
machine.
The stock thus obtained should be fairly white, depending upon the grade
of tallow used and slightly alkaline to an alcoholic phenolphthalein
solution. If removed at exactly the neutral point or with a content of
free fat the soap will sooner or later develop rancidity. The soap thus
obtained is an ordinary tallow base, and the one by far greatest used in
the manufacture of toilet soaps. The percentage of cocoanut oil
indicated is not fixed and may readily be varied, while in fine toilet
soap the rosin is usually eliminated.
In the manufacture of full boiled soda soaps in which no glycerine is
obtained as a by-product, it being retained in the soap itself, the soap
formed is known as a "run" soap. The process is used most extensively in
the manufacture of marine soaps by which the method may be best
illustrated. This soap is known as marine soap because of its property
of readily forming a lather with salt water and is mostly consumed
aboard vessels.
Public-domain text, read in full here on John Shaqi.
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