Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.Thomssen, Edgar George
Science
Soap-Making Manual: A Practical Handbook on the Raw Materials, Their Manipulation, Analysis and Control in the Modern Soap Plant.
Thomssen, Edgar George
Soap
To carry out the process, the caustic potash and carbonate of potash are
dissolved and placed in the kettle together with the soda lye, and the
oils added. This is most satisfactorily accomplished by being finished
the day before the boiling is begun. The next day the boiling is begun
and water added to bring the soap up to the desired percentage of fatty
acid, due allowance being made for the water formed by the condensation
of the open steam in boiling. Care must be taken that the soap in the
kettle does not swell and run over during the saponification. A good
procedure is to use open steam for a period of about two hours, then
close the valve and allow the saponification to continue without
boiling, and repeat this until it is entirely saponified. After the
saponification has been completed the soap is briskly boiled all day and
the proper corrections made; that is, if too alkaline, more oil is
added, and if free fat is present, more potash. About 2 per cent.
carbonate of potash is the proper amount for a soap containing 50 per
cent. fatty acid. The soap is sampled by allowing it to drop on a clean,
cold glass surface. In so doing, the soap should not slide or slip over
the glass surface when pressed thereon, but should adhere to the glass,
or it is too alkaline. A sample worked between the fingers showing too
much stringiness should have more strong potash and oil added. A sample
taken out in a pail and allowed to cool over night will serve as a guide
as to the body of the soap in the kettle. When the soap has thus been
properly finished it is run into barrels.
For an automobile soap the following is a good working formula:
Corn oil 1,000 parts
Potash lye, 31-1/2 degs. B. 697 parts
Proceed as in the directions just given for textile soap in placing
charge in the kettle. When the kettle is boiling up well, shut off the
steam and the saponification will complete itself. The soap may be run
into the barrels the next day.
A heavy soap with a smaller percentage of fat may be made as follows:
Corn oil 1,000 parts
Potash lye, 24-1/2 degs. B. 900 parts
Boil until the soap bunches, and shovel the finished soap into barrels.
Upon standing it will clear up. By the addition of more water the yield
of soap per pound of oil may be run up to 300 per cent.
After soft soaps have been allowed to stand for some time the phenomenon
known as "figging" often occurs. This term is applied to a
crystalline-like formation, causing spots of a star-like shape
throughout the soap. This is undoubtedly due to the stearine content of
the soap crystallizing out as it cools, and forming these
peculiarly-shaped spots. It more generally occurs in the winter and may
be produced artificially by adding a small quantity of soda to the
potash lye before saponification.
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