_Ulmin Substances; Sour Humus_ (Germ. Rohhumus).—In the presence of so much moisture or liquid water as will materially impede the access of air, and with the concurrence of reasonably low temperatures, the organisms that at first take the chief role in the transformation of the vegetable tissues into humus-like substances are bacteria. But the antiseptic nature of the compounds thus formed[36] soon puts an end to their activity, and thereafter the process seems to be a purely chemical one, and very slow. In peat bogs, the transition from the fresh, dead stems and roots to brown peat is easily followed downward, white cellulose fibers remaining apparently unchanged to some depth; so that such fiber has been used for tissues and paper. The solid decomposition-products are brown substances, partly soluble in water and imparting to it a brown or coffee color (frequently seen in the drains of marshes) and an acid reaction; the latter due to ulmic (as well as apocrenic) acid, readily soluble in caustic and carbonated alkalies, and forming insoluble salts with the earths and metals; while another portion, ulmin, is insoluble in the same, but gradually becomes soluble by oxidation. [36] The antiseptic properties of sour humus are well exemplified in the perfect state of preservation in which the remains of animals, wood implements, etc., are found in bogs into which they have sunk in prehistoric times. The gaseous products formed under these conditions are carbonic dioxid and “marsh gas” (methan, CH₄), the former predominating in the early stages; while later, the carburetted hydrogen predominates, rendering the gas readily inflammable. _Sour Soils._—The “sour” soils thus produced in nature in presence of excess of water bear only “sour” growth, such as sedges and rushes, of little agricultural value; they usually require reclamation processes before becoming adapted to ordinary crops. In old forests of northern climates a peaty and more or less acid layer is sometimes formed on the surface, above the black woods-earth, and retards somewhat the full production of such land when taken into cultivation.[37] [37] See Müller, Natürliche Humusformen. Marshes and swamps, both fresh and salt, as above stated usually show coffee-colored waters, which are also characteristic of the streams that drain them, until by intermixture with waters containing lime salts, the ulmic substances are neutralized and precipitated. Such neutralization, preferably by means of lime, is the first step towards the reclamation of lands bearing “sour” vegetation. The acid reaction characterizing the ulmic substances is also characteristic of many woodlands, notably in the United States of the soils of the “Long-leaf-pine” region of the Cotton States, both upland and lowland, as well as of many deciduous forests in northern climates. Hence liming, whether artificial or natural, effects a most notable improvement, together with a marked change of vegetation, in these lands.